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81118 Vanadium(V) trichloride oxide, V+5 28.5% min

CAS Number
7727-18-6
Synonyms
Vanadium oxytrichloride
Vanadyl trichloride

Stock No. Size Price ($) Quantity Availability
81118-09 10g 10.50
81118-22 100g 43.60
81118-36 500g 189.00
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Vanadium(V) trichloride oxide, V+5 28.5% min

MDL
MFCD00011459
EINECS
231-780-2

Chemical Properties

Formula
VOCl3
Formula Weight
173.30
Form
Liquid
Melting point
-77°
Boiling Point
126-127°
Density
1.829
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Miscible with benzene, dichloromethane and hexane.

Applications

Vanadium(V) trichloride oxide is used as a catalyst in olefin polymerization reaction, especially for the production of ethylene-propylene rubber. It is also used to synthesis organovanadium compounds and as a mordant in dyeing. It acts as a precursor to prepare vanadium pentoxide, vanadyl dichloride and dioxovanadium monochloride. Further, it serves as a reagent and a strong oxidizing agent in organic synthesis.

Notes

Moisture sensitive. Incompatible with bases, amines, strong oxidizing agents and alcohols.

Literature References

Gao, P.; Wall, C.; Zhang, L.; Reddy, M. A.; Fichtner, M. Vanadium oxychloride as electrode material for sodium ion batteries. Electrochem. Commun. 2015, 60, 180-184.

Malkov, A. A.; Malygin, A. A. Synthesis and thermochemical transformations of vanadium oxychloride groups on a silica surface. Russ. J. Phys. Chem. A 2014, 88 (3), 530-536.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H314-H318

Toxic if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Do not breathe dusts or mists. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,9927
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2827.49
TSCA
Yes
RTECS
YW2975000

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