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81135 Vanadium(III) bromide, 99.5% (metals basis)

CAS Number
13470-26-3
Synonyms
Vanadium tribromide

Stock No. Size Price ($) Quantity Availability
81135-04 2g 55.50
81135-09 10g 226.00
81135-18 50g 1000.00
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Vanadium(III) bromide, 99.5% (metals basis)

MDL
MFCD00049695
EINECS
236-736-6

Chemical Properties

Formula
VBr3
Formula Weight
290.67
Form
Crystalline
Melting point
dec.
Density
4.00^1^8
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in water and tetrahydrofuran.

Applications

Vanadium(III) bromide is used as a catalyst for C(sp3)-H fluorination reactions especially the benzylic fluorination.

Notes

Moisture sensitive. Incompatible with acids.

Literature References

Xia, J. B.; Ma, Y.; Chen, C. Vanadium-catalyzed C(sp3)-H fluorination reactions. Org. Chem. Front. 2014, 1 (5), 468-472.

Winardi, S.; Poon, G.; Ulaganathan, M.; Parasuraman, A.; Yan, Q.; Wai, N.; Lim, Y. M.; Skyllas-Kazacos, M. Effect of Bromine Complexing Agents on the Performance of Cation Exchange Membranes in Second-Generation Vanadium Bromide Battery. ChemPlusChem 2015, 80 (2) , 376-381.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2827.59
TSCA
Yes
RTECS
YW2750000

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