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87324 Methylmagnesium bromide, 3M in ether

CAS Number
75-16-1
Synonyms

Stock No. Size Price ($) Quantity Availability
87324-AP 500ml 141.00
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Methylmagnesium bromide, 3M in ether

MDL
MFCD00000041
EINECS
200-844-1

Chemical Properties

Formula
CH3BrMg
Formula Weight
119.26
Form
Liquid
Flash Point
-40°(-40°F)
Density
1.035
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

Methylmagnesium bromide is widely used in organic synthesis.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. It is sensitive to heat, air and moisture. Incompatible with oxygen, oxidizing agents, alcohols and acids.

Literature References

Masuhiko Tamura.; Jay K. Kochi. Vinylation of Grignard reagents. Catalysis by iron. J. Am. Chem. Soc. 1971, 93 (6), 1487-1489.

Dietmar Seyferth.; Bela Prokai. The Reduction of gem-Dibromocyclopropanes to Monobromocyclopropanes with Methylmagnesium Bromide. J. Org. Chem. Soc. 1966, 31 (6), 1702-1704.

GHS Hazard and Precautionary Statements

Hazard Statements: H224-H260-H302-H314-H318-H335-H336

Extremely flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P231+P232-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Explosion risk in case of fire. Fight fire with normal precautions from a reasonable distance. Evacuate area. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
Yes

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