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87326 Phenylmagnesium bromide, 3M in ether

CAS Number
100-58-3
Synonyms

Stock No. Size Price ($) Quantity Availability
87326-AE 100ml 48.50
87326-AP 500ml 128.00
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Phenylmagnesium bromide, 3M in ether

MDL
MFCD00000038

Chemical Properties

Formula
C6H5MgBr
Formula Weight
181.31
Form
Liquid
Density
1.14
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Light Sensitive. May form a Precipitate. Store under Argon. Ambient temperatures.
Solubility
Miscible with terahydrofuran.

Applications

Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

Notes

Air, moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, strong oxidizing agents, strong acids and alcohols.

Literature References

Majumdar, P.; Mack, J.; Nyokong, T. Synthesis, characterization and photophysical properties of an acenaphthalene fused-ring-expanded NIR absorbing aza-BODIPY dye. RSC Adv. 2015, 5 (95), 78253-78258.

Manning, K. B.; Shtukenberg, A. G.; Nichols, S. M.; Kahr, B.; Weck, M. Synthesis and liquid crystalline behavior of bulky poly(methacrylamide)s. J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (22), 2563-2568.

GHS Hazard and Precautionary Statements

Hazard Statements: H224-H261-H314-H318-H336

Extremely flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage. May cause drowsiness or dizziness.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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