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87839 Sodium cyanoborohydride, 95%

CAS Number
25895-60-7
Synonyms
Sodium cyanotrihydridoborate

Stock No. Size Price ($) Quantity Availability
87839-06 5g 24.00
87839-14 25g 86.40
87839-22 100g 317.00
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Sodium cyanoborohydride, 95%

MDL
MFCD00003516
EINECS
247-317-2

Chemical Properties

Formula
NaBH3CN
Formula Weight
62.84
Form
Powder
Melting point
>300° dec.
Density
1.20
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in water, THF, methanolSoluble in water, diglyme, tetrahydrofuran and methanol. Slightly soluble in dimethyl sulfoxide. Insoluble in diethyl ether.

Applications

Selective reducing agent for aldehydes, ketones, oximes, enamines. Reductive animation of ketones, aldehydes. Reductive alkylation of amines, hydrazines Sodium cyanoborohydride is used as a reagent involved in the reductive amination of aldehydes, ketones, oximes and enamines. It is also used in the reductive alkylation of amines and hydrazines. It acts as a catalyst in the preparation of phenolate-bridged dilanthanum(III) complex. In addition, it is used in the conversion of imines to amines. It plays an important role in the reductive deoxygenation of ketones.

Notes

Moisture sensitive. Incompatible with strong acids, water and strong oxidizing agents.

Literature References

Long, Y.; Wood, T. D. Immobilized Pepsin Microreactor for Rapid Peptide Mapping with Nanoelectrospray Ionization Mass Spectrometry. J. Am. Soc. Mass. Spectrom. 2015, 26 (1), 194-197.

Koehler, C. J.; Arntzen, M. Ø.; Thiede, B. The impact of carbon-13 and deuterium on relative quantification of proteins using stable isotope diethyl labeling. Rapid Commun. Mass Spectrom. 2015, 29 (9), 830-836.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H261-H300-H310-H314-H330

Flammable solid. In contact with water releases flammable gas. Fatal if swallowed. Fatal in contact with skin. Causes severe skin burns and eye damage. Fatal if inhaled.

Precautionary Statements: P210-P223-P231+P232-P240-P241-P260-P262-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8606
Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2850.00
TSCA
Yes

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