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87913 Thallium(III) trifluoroacetate, 95%

CAS Number
23586-53-0
Synonyms
Thallic trifluoroacetate

Stock No. Size Price ($) Quantity Availability
87913-04 2g 29.20
87913-09 10g 115.00
87913-18 50g 455.00
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Thallium(III) trifluoroacetate, 95%

MDL
MFCD00000414
EINECS
245-761-1

Chemical Properties

Formula
Tl(OOCCF3)3
Formula Weight
543.42
Form
Solid
Melting point
213° dec.
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water (decomposes).

Applications

Thallium(III) trifluoroacetate is an oxidizing agent used in the synthesis of S-substituted cysteine peptides and proteins containing disulfide bonds.

Notes

Keep container tightly closed in a dry and well-ventilated place. Store at 4°C. Incompatible with strong oxidizing agents. Air sensitive. It is hygroscopic in nature.

Literature References

Alexander McKillop.; Andrew G. Turrell.; Derek W. Young.; Edward C. Taylor. Thallium in organic synthesis. 58. Regiospecific intermolecular oxidative dehydrodimerization of aromatic compounds to biaryls using thallium(III) trifluoroacetate. J. Am. Chem. Soc. 1980, 102 (21), 6504-6512.

Alexander McKillop.; John D. Hunt.; Michael J. Zelesko.; Joanna S. Fowler.; Edward C. Taylor.; George McGillivray.; Frank Kienzle. Thallium in organic synthesis. XXII. Electrophilic aromatic thallation using thallium(III) trifluoroacetate. Simple synthesis of aromatic iodides. J. Am. Chem. Soc. 1971, 93 (19), 4841-4844.

GHS Hazard and Precautionary Statements

Hazard Statements: H300+H330-H373

Fatal if swallowed. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P271-P284-P301+P310-P304+P340-P310-P314-P330-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes

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