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88614 Silver nitrate, Acculute Standard Volumetric Solution, Final Concentration 0.1N

CAS Number
7761-88-8
Synonyms

Stock No. Size Price ($) Quantity Availability
88614-LQ 1unit 83.60
88614-LS 6units 438.00
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Silver nitrate, Acculute Standard Volumetric Solution, Final Concentration 0.1N

MDL
MFCD00003414
EINECS
231-853-9

Chemical Properties

Formula
AgNO3
Formula Weight
169.87
Form
Liquid
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Miscible with water, alcohol and aqueous ammonia.

Applications

Silver nitrate 0.1N standard volumetric solution is used for volumetric analysis in laboratories. It is widely used as an analytical reagent owing to its immediate reaction with halide ions forming insoluble precipitate of silver(I) halides.

Notes

One unit makes one liter of 0.1N solution after dilutionSensitive to light. Store in light resistant containers. Color changes to grey or greyish black on exposure to light or air in the presence of organic matter.

Literature References

Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).

Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).

In combination with Br2 or I2 in refluxing methanol, brings about the rearrangement of acetophenones to methyl arylacetates, a reaction previously induced by thallium(III) nitrate: J. Chem. Soc., Perkin 1, 235 (1982):

The Hunsdiecker reaction of Ag salts of carboxylic acids with Br2 provides alkyl bromides with one less carbon atom which is lost as CO2; see, e.g.: Org. Synth. Coll., 3, 578 (1955). Reviews: Chem. Rev., 56, 219 (1956); Org. React., 9, 332 (1957). Compare also Mercury(II)­ oxide, A16157.

For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethyl­acetic acid, A10776.

Brodsgaard, A.; Nielsen, T.; Molgaard, U.; Pryds, O.; Pedersen, P. Treating umbilical granuloma with topical clobetasol propionate cream at home is as effective as treating it with topical silver nitrate in the clinic. Acta Paediatr. 2015, 104 (2), 174-177.

Yang, J. Y.; Zheng, C. M.; Wang, Y. Q.; Guo, M. L. Phosphate-assisted one-pot synthesis of silver phosphate-mesoporous silica composite from sodium silicate and silver nitrate. Microporous Mesoporous Mater 2015, 204, 58-61.

GHS Hazard and Precautionary Statements

Hazard Statements: H271-H314-H335

May cause fire or explosion; strong oxidizer. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.21
TSCA
Yes

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