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Silver trifluoromethanesulfonate is useful in halide abstraction. It helps in activating sulphur protecting groups at the anomeric centres of carbohydrates in the presence of iodine. It is employed as a triflating agent in combination with Palladium compounds, as a catalyst for cross coupling reactions, and in several organic transformation reactions. Polyurethanes prepared from silver triflate exhibit high permeability and selectivity towards olefins in their separation from paraffin mixtures. Polyethylene oxide - silver triflate composites find application in humidity sensors.
Abbiati, F.; Rossi, E. Silver and Gold Catalyzed Multicomponent Reactions. Beilstein J. Org. Chem. 2014, 10, 481-513.
Zheng, D.; Li, S.; Wu, J. An Unexpected Silver Triflate Catalyzed Reaction of 2-Alkynylbenzaldehyde with 2-Isocyanoacetate. Org. Lett. 2012, 14 (11), 2655-2657.
Gondaliya, N.; Kanchan, D. K.; Sharma, P.; Joge, P. Structural and Conductivity Studies of Poly(Ethylene Oxide)-Silver Triflate Polymer Electrolyte System. Materials Sciences and Applications 2011, 2, 1639-1643.
Kim, J. H.; Min, B. R.; Won, J.; Joo, S. H.; Kim, H. S.; Kang, Y. S. Role of Polymer Matrix in Polymer/Silver Complexes for Structure, Interactions, and Facilitated Olefin Transport. Macromolecules 2003, 36, 6183-6188.
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P273-P280-P303+P361+P353-P305+P351+P338-P310a
Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor