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89035 Diethylaluminum chloride, 96%, 25% w/w in heptane

CAS Number
96-10-6
Synonyms

Stock No. Size Price ($) Quantity Availability
89035-ND (c)25g 128.00
89035-NF (c)100g 474.00
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Diethylaluminum chloride, 96%, 25% w/w in heptane

MDL
MFCD00000459

Chemical Properties

Formula
C4H10AlCl
Formula Weight
120.56
Form
Liquid
Flash Point
-18°(-1°F)
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Miscible with hexane.

Applications

Diethylaluminum chloride is used as a catalyst in thermoplastic polymers and as a reactant in the preparation of aluminum-phosphorus compounds. It is used in Ziegler-Natta polymerization process for vinyl, olefin, diene polymerizations, linear oligomerization and cyclization of unsaturated hydrocarbon. Further, it serves as an intermediate for organometallic compounds. In addition to this, it acts as an alkylation catalyst and Lewis-acid catalyst in Diels-Alder reactions.

Notes

Sold on Diethylaluminum chloride contained basisAir and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, water, acids, bases, alcohols, oxygen and organic halides.

Literature References

Yoon, H.; Lee, Y. Copper-Catalyzed Electrophilic Amination of Heteroarenes via C-H Alumination. J. Org. Chem. 2015, 80 (20), 10244-10251.

Murgia, F.; Weldekidan, E. T.; Stievano, L.; Monconduit, L.; Berthelot, R. First investigation of indium-based electrode in Mg battery. Electrochem. Commun. 2015, 60, 56-59.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H250-H260-H304-H314-H335-H336

Highly flammable liquid and vapour. Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which may ignite spontaneously. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P222-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P302+P334-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Immerse in cool water/wrap in wet bandages. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Brush off loose particles from skin. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.2
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
BD0558000

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