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89149 Borane-dimethylamine complex, 97%

CAS Number
74-94-2
Synonyms
Dimethylamine borane

Stock No. Size Price ($) Quantity Availability
89149-14 25g 60.60
89149-22 100g 174.00
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Borane-dimethylamine complex, 97%

MDL
MFCD00051068
EINECS
200-823-7

Chemical Properties

Formula
BH3.NH(CH3)2
Formula Weight
58.92
Form
Crystalline
Melting point
36°
Boiling Point
59-65°/1-2mm
Density
0.69
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Soluble in methanol, water, ethanol, 2-propanol and terahydrofuran.

Applications

Borane-dimethylamine complex is used in a nickel-catalyzed reduction of electron-deficient aryl tosylates. It also serves as a reducing agent in electrolytic deposition of metals, alloys, semiconductors and insulators.

Notes

Store in a cool place. Incompatible with acids, oxidizing agents, heavy metal salts and oxygen.

Literature References

Duman, S.; Masjedi, M.; Özkar, S. Highly active and long lived homogeneous catalyst for the dehydrogenation of dimethylamine borane starting with ruthenium(III) acetylacetonate and oleylamine precatalyst. J. Mol. Catal. A: Chem. 2016, 411, 9-18.

Barın, E. Ü.; Masjedi, M.; Özkar, S. A New Homogeneous Catalyst for the Dehydrogenation of Dimethylamine Borane Starting with Ruthenium(III) Acetylacetonate. Materials 2015, 8 (6), 3155-3167.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H301-H311-H330-H314-H318

Flammable solid. Toxic if swallowed. Toxic in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a

IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2942.00
TSCA
Yes
RTECS
IP9450000

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