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95838-16-7 - Cerium(IV) sulfate hydrate, 98% - Ceric sulfate hydrate - A10142 - Alfa Aesar

A10142 Cerium(IV) sulfate hydrate, 98%

CAS Number
95838-16-7
Synonyms
Ceric sulfate hydrate

Size Price ($) Quantity Availability
50g 36.67
250g 107.12
1000g 360.50
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Cerium(IV) sulfate hydrate, 98%

MDL
MFCD00149427
EINECS
237-029-5

Chemical Properties

Formula
Ce(SO4)2•xH2O
Formula Weight
332.24(anhy)
Melting point
195° dec.
Density
3.01
Solubility
Soluble in water.

Applications

Cerium(IV) sulfate hydrate is used as a general application for chemical intermediate.

Notes

Store in cool, dry conditions in well sealed containers. keep container tightly closed

Literature References

M. P. Singh; H. S. Singh; M. K. Verma. Kinetics and mechanism of the ruthenium(III) chloride catalyzed oxidation of butanone-2 and pentanone-3 by cerium(IV) sulfate in aqueous sulfuric acid medium. J. Phys. Chem. 1980, 84,(3), 256-259.

Oxidizing agent which has been used for the generation of o-benzoquinone from catechol: Liebigs Ann. Chem., 712, 214 (1968).

Promotes the formation of radicals from dialkyl malonates, which undergo substitution reactions with furans and thiophenes: Heterocycles, 27, 2627 (1988).

In the presence of oxygen, oximes can be converted to the parent carbonyl compounds in good yield: Appl. Organomet. Chem., 13, 867 (1999).

In combination with iodine in EtOH, 2-alkylcycloalkanones are ring-opened to ethyl keto esters: J. Chem. Res. (Synop.), 122 (1999).

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H272

Causes severe skin burns and eye damage. May intensify fire; oxidizer.

Precautionary Statements: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,1990
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2846.10
TSCA
Yes
RTECS
WS6960000

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