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Cerium(IV) sulfate hydrate is used as a general application for chemical intermediate.
M. P. Singh; H. S. Singh; M. K. Verma. Kinetics and mechanism of the ruthenium(III) chloride catalyzed oxidation of butanone-2 and pentanone-3 by cerium(IV) sulfate in aqueous sulfuric acid medium. J. Phys. Chem. 1980, 84,(3), 256-259.
Oxidizing agent which has been used for the generation of o-benzoquinone from catechol: Liebigs Ann. Chem., 712, 214 (1968).
Promotes the formation of radicals from dialkyl malonates, which undergo substitution reactions with furans and thiophenes: Heterocycles, 27, 2627 (1988).
In the presence of oxygen, oximes can be converted to the parent carbonyl compounds in good yield: Appl. Organomet. Chem., 13, 867 (1999).
In combination with iodine in EtOH, 2-alkylcycloalkanones are ring-opened to ethyl keto esters: J. Chem. Res. (Synop.), 122 (1999).
Hazard Statements: H272-H314-H335
May intensify fire; oxidizer. Causes severe skin burns and eye damage. May cause respiratory irritation.
Precautionary Statements: P210-P220-P221-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant