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A10150 2-Iodoanisole, 99%

CAS Number
529-28-2
Synonyms
2-Methoxyiodobenzene

Stock No. Size Price ($) Quantity Availability
A10150-14 25g 39.50
A10150-22 100g 97.20
A10150-36 500g 383.00
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2-Iodoanisole, 99%

MDL
MFCD00001039
EINECS
208-456-4

Chemical Properties

Formula
C7H7IO
Formula Weight
234.04
Boiling Point
240-242°
Flash Point
>110°(230°F)
Density
1.800
Refractive Index
1.6220
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Miscible with alcohol, chloroform and diethyl ether. Insoluble in water.

Applications

2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

Notes

Light Sensitive, store in dark. Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literature References

Dawei Yue et. al.Synthesis of 2,3-disubstituted benzo[b]furans by the palladium-catalyzed coupling of o-iodoanisoles and terminal alkynes, followed by electrophilic cyclization. Journal of Organic Chemistry. 2005, 70 (25), 10292-10296 .

Adam Morel et. al. Palladium-catalyzed asymmetric Heck arylation of 2,3-dihydrofuran--effect of prolinate salts. Dalton Transactions. 2013, 42 (4), 1215-1222.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,5028
Beilstein
1860243
Harmonized Tariff Code
2909.30
TSCA
Yes

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