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529-28-2 - 2-Iodoanisole, 99% - 2-Methoxyiodobenzene - A10150 - Alfa Aesar

A10150 2-Iodoanisole, 99%

CAS Number
529-28-2
Synonyms
2-Methoxyiodobenzene

Size Price ($) Quantity Availability
25g 37.90
100g 80.46
500g 327.60
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2-Iodoanisole, 99%

MDL
MFCD00001039
EINECS
208-456-4

Chemical Properties

Formula
C7H7IO
Formula Weight
234.04
Boiling Point
240-242°
Flash Point
>110°(230°F)
Density
1.800
Refractive Index
1.6220
Sensitivity
Light Sensitive
Solubility
Miscible with alcohol, chloroform and diethyl ether. Insoluble in water.

Applications

2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

Notes

Light Sensitive, store in dark. Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literature References

Dawei Yue et. al.Synthesis of 2,3-disubstituted benzo[b]furans by the palladium-catalyzed coupling of o-iodoanisoles and terminal alkynes, followed by electrophilic cyclization. Journal of Organic Chemistry. 2005, 70 (25), 10292-10296 .

Adam Morel et. al. Palladium-catalyzed asymmetric Heck arylation of 2,3-dihydrofuran--effect of prolinate salts. Dalton Transactions. 2013, 42 (4), 1215-1222.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5028
Beilstein
1860243
Harmonized Tariff Code
2909.30
TSCA
Yes

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