Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A10186 3-Bromo-2-butanone, 97%, stab. with <1% magnesium oxide

CAS Number
814-75-5
Synonyms

Stock No. Size Price ($) Quantity Availability
A10186-09 10g 103.00
A10186-18 50g 380.00
A10186-30 250g 1515.00
Add to Cart Bulk/Specialty Print Quote View Item

3-Bromo-2-butanone, 97%, stab. with <1% magnesium oxide

MDL
MFCD00013538
EINECS
212-404-6

Chemical Properties

Formula
C4H7BrO
Formula Weight
151.01
Boiling Point
69-70°/70mm
Flash Point
>100°(212°F)
Density
1.438
Refractive Index
1.4590
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with dichloromethane.

Applications

3-Bromo-2-butanone is involved in the preparation of o-isopropyl S-3-oxobutan-2-yl dithiocarbonate by reaction with potassium o-isopropylxanthate, which on treatment with sulfuric acid gives 4,5-dimethyl-1,3-dithiol-2-one .

Notes

Incompatible with strong oxidizing agents, strong bases and strong reducing agents.

Literature References

Has been used in an improved synthesis of 5-halopyrimidines by the reaction of ɑ -halo ketones with nitriles: Synthesis, 1053 (1992).

Goel, R.; Luxami, V.; Paul, K. Recent advances in development of imidazo[1,2-a]pyrazines: synthesis, reactivity and their biological applications. Org. Biomol. Chem. 2015, 13 (12), 3525-3555.

Ghosh, A. C.; Reinhardt, J. K.; Kindermann, M. K.; Schulzke, C. The ring opening reaction of 1,3-dithiol-2-one systems is fully reversible. Chem. Commun. 2014, 50 (70), 10102-10104.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H312-H314-H332

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
906773
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2914.79
TSCA
Yes
RTECS
EL7005000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware