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10486-00-7 - Sodium perborate tetrahydrate, 97% - A10189 - Alfa Aesar

A10189 Sodium perborate tetrahydrate, 97%

CAS Number
10486-00-7
Synonyms

Size Price ($) Quantity Availability
100g 27.90
500g 89.73
2500g 323.20
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Sodium perborate tetrahydrate, 97%

MDL
MFCD00149231
EINECS
239-172-9

Chemical Properties

Formula
NaBO3•4H2O
Formula Weight
153.86 (81.84anhy)
Melting point
60° dec.
Density
1.73
Sensitivity
Hygroscopic
Solubility
Soluble in water.

Applications

Sodium perborate tetrahydrate is considered as a source of active hydrogen used in detergents, cleaning products, laundry detergents and bleaches. It finds application as a tooth bleaching agent utilized for tooth. It has antiseptic properties and acts as disinfectant as well as preservative in eye drops. Further, it is mixed with suitable activator, tetraacetylethylenediamine in order to release oxygen at lower temperatures.

Notes

Moisture sensitive.Incompatible with metals, metallic salts, acids, bases and reducing agents.

Literature References

Useful, inexpensive oxidant. Reviews: Chemtech, 566 (1991); Tetrahedron, 51, 6145 (1995); Synthesis, 1325 (1995); J. Chem. Soc., Perkin 1, 471 (2000). Examples: Oxidation of secondary alcohols to ketones, and ɑ-hydroxy acids to keto acids: Synthesis, 765 (1989). Mild epoxidation of ɑß-unsaturated ketones: Synth. Commun., 19, 3579 (1989); Tetrahedron Lett., 36, 663 (1995). Partial hydrolysis of nitriles to amides: Tetrahedron, 45, 3299 (1989); Synth. Commun., 20, 563 (1990). Oxidation (in AcOH) of sulfides to sulfoxides or sulfones, arylamines to nitro compounds, and Baeyer-Villiger oxidation of ketones to esters: Tetrahedron, 43, 1753 (1987). Oxidation (in AcOH) of aromatic aldehydes to acids: Tetrahedron, 45, 3299 (1989); or oximes to nitro compounds: Synlett, 337 (1992). Oxidative conversion of organoboranes to alcohols: Org. Synth. Coll., 9, 522 (1998).

In combination with triflic acid for hydroxylation of aromatics: Synlett, 39 (1991).

In combination with acetic anhydride, cyclic acetals are cleaved to their respective esters: Synlett., 329 (1995).

For phase-transfer oxidation of alcohols to ketones, catalyzed by Chromium(VI)­ oxide, 12522, see: Synth. Commun., 21, 575 (1991).

For a brief feature on uses in synthesis, see: Synlett, 2513 (2006).

Qin, S.; Yin, B.; Zhang, Y.; Zhang, Y. Leaching kinetics of szaibelyite ore in NaOH solution. Hydrometallurgy 2015, 157, 333-339.

Hematian, S.; Hormozi, F. Drying kinetics of coated sodium percarbonate particles in a conical fluidized bed dryer. Powder Technol. 2015, 269, 30-37.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H360-H318-H302-H335

May intensify fire; oxidizer. May damage fertility or the unborn child. Causes serious eye damage. Harmful if swallowed. May cause respiratory irritation.

Precautionary Statements: P221-P210-P201-P220-P261-P280-P281-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,8652
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2840.30
TSCA
Yes
RTECS
SC7350000

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