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13670-99-0 - 2',6'-Difluoroacetophenone, 98% - A10220 - Alfa Aesar

A10220 2',6'-Difluoroacetophenone, 98%

CAS Number
13670-99-0
Synonyms

Size Price ($) Quantity Availability
1g 36.73
5g 116.66
25g 462.60
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2',6'-Difluoroacetophenone, 98%

MDL
MFCD00000328
EINECS
237-151-9

Chemical Properties

Formula
C8H6F2O
Formula Weight
156.13
Boiling Point
76-79°/15mm
Flash Point
76°(168°F)
Density
1.195
Refractive Index
1.4810
Solubility
Slightly soluble in water.

Applications

2?,6?-Difluoroacetophenone was used in the synthesis of 2-amino-4-alkyl- and 2-amino-4-arylquinazolines.

Notes

Store in cool, dry conditions in well sealed containers. keep container tightly closed. Store away from strong oxidizing agents.

Literature References

Hynes JB, et al. Synthesis of 2-aminoquinazolines from ortho-fluoroketones. J. Heterocycl. Chem. 1995, 32,(4), 1185-1187.

Kawamoto K, et al. Ruthenium-catalyzed arylation of fluorinated aromatic ketones via< i> ortho-selective carbon-fluorine bond cleavage. Tetrahedron Lett. 2011, 52,(44), 5888-5890.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
2046068
Harmonized Tariff Code
2914.70
TSCA
No

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