Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A10220 2',6'-Difluoroacetophenone, 98%

CAS Number
13670-99-0
Synonyms

Stock No. Size Price ($) Quantity Availability
A10220-03 1g 42.30
A10220-06 5g 133.00
A10220-14 25g 439.00
Add to Cart Bulk/Specialty Print Quote View Item

2',6'-Difluoroacetophenone, 98%

MDL
MFCD00000328
EINECS
237-151-9

Chemical Properties

Formula
C8H6F2O
Formula Weight
156.13
Boiling Point
76-79°/15mm
Flash Point
76°(168°F)
Density
1.195
Refractive Index
1.4810
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

2?,6?-Difluoroacetophenone was used in the synthesis of 2-amino-4-alkyl- and 2-amino-4-arylquinazolines.

Notes

Store in cool, dry conditions in well sealed containers. keep container tightly closed. Store away from strong oxidizing agents.

Literature References

Hynes JB, et al. Synthesis of 2-aminoquinazolines from ortho-fluoroketones. J. Heterocycl. Chem. 1995, 32,(4), 1185-1187.

Kawamoto K, et al. Ruthenium-catalyzed arylation of fluorinated aromatic ketones via< i> ortho-selective carbon-fluorine bond cleavage. Tetrahedron Lett. 2011, 52,(44), 5888-5890.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H315-H319-H335

Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2046068
Harmonized Tariff Code
2914.79
TSCA
No

Recommended

  • L20266

    2,4-Difluorophenylglyoxal hydrate, 95%, dry wt. basis

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware