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Trimethyl orthobenzoate was used in the preparation of 5-phenyl-4,6-dipyrrin and 2,3-orthoester derivatives of ethyl-1-thio-α-L-rhamnopyranoside. It reacts with indole to prepare indol-3-yl-phenyl-methanone.
R G Hicks; L Ohrström; G W Patenaude. Spin distributions, ring conformations, and spiroconjugation in "phosphaverdazyl" radicals. Inorganic Chemistry. 2001, 40 (8), 1865-1870.
Reaction with BF3 etherate gives the selective alkylating agent, phenyldimethoxycarbenium tetrafluoroborate, stable for a few weeks at 0o: Synth. Commun., 19, 2307 (1989).
Hazard Statements: H227-H315-H319-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210u-P261-P280a-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.