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75-97-8 - Pinacolone, 97% - tert-Butyl methyl ketone - 3,3-Dimethyl-2-butanone - A10289 - Alfa Aesar

A10289 Pinacolone, 97%

CAS Number
75-97-8
Synonyms
tert-Butyl methyl ketone
3,3-Dimethyl-2-butanone

Size Price ($) Quantity Availability
100g 78.66
500g 313.12
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Pinacolone, 97%

MDL
MFCD00008846
EINECS
200-920-4

Chemical Properties

Formula
C6H12O
Formula Weight
100.16
Melting point
-53°
Boiling Point
105-106°
Flash Point
5°(41°F)
Density
0.803
Refractive Index
1.3970
Solubility
Miscible with water, chloroform, ethanol, ether, acetone and carbon tetrachloride.

Applications

Pinacolone is a precursor to triazolylpinacolone, triadimefon, paclobutrazol, uniconazole and metribuzin. Furthermore, it acts as an intermediate for biologically active products such as antibacterial, antifungal, antiviral and antituberculous products. It is an important ketone in organic chemistry and participates in condensation, hydrogenation and reductive amination reactions.

Notes

Incompatible with strong oxidizing agents.

Literature References

Gelat, F.; Richard, V.; Berger, O.; Montchamp, J. L. Development of a New Family of Chiral Auxiliaries. Org. Lett. 2015, 17 (8), 1819-1821.

Braun, M.; Ito, T.; Hoshino, R.; Iinuma, M. Lithium Enolates:'Capricious' Structures-Reliable Reagents for Synthesis. Helv. Chim. Acta. 2015, 98 (1), 1-31.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302

Highly flammable liquid and vapour. Harmful if swallowed.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P303+P361+P353-P301+P312-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7440
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2914.19
TSCA
Yes
RTECS
EL7700000

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