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104-53-0 - 3-Phenylpropionaldehyde, 95% - Hydrocinnamaldehyde - 3-Phenylpropanal - A10367 - Alfa Aesar

A10367 3-Phenylpropionaldehyde, 95%

CAS Number
104-53-0
Synonyms
Hydrocinnamaldehyde
3-Phenylpropanal

Size Price ($) Quantity Availability
50g 35.58
250g 115.95
1000g 370.40
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3-Phenylpropionaldehyde, 95%

MDL
MFCD00007021
EINECS
203-211-8

Chemical Properties

Formula
C9H10O
Formula Weight
134.18
Melting point
-42°
Boiling Point
222-223°
Flash Point
95°(203°F)
Density
1.017
Refractive Index
1.5230
Sensitivity
Air Sensitive
Solubility
Miscible with chloroform, dichloromethane, ethyl acetate, alcohol and ether. Immiscible with water.

Applications

3-Phenylpropionaldehyde is used as a flavoring agent. It is also used in the preparation of cinnamaldehyde, 2-chloro hydrocinnamaldehyde by alfa chlorination and mixture of homopropargyl alcohols. It serves as a precursor for the synthesis of mixture of syn- and anti-beta-hydroxyallylsilanes by hydroboration of allenylsilane. It is also involved in the catalytic asymmetric cyanosilylation to prepare (2S)-2-hydroxy-4-phenylbutanenitrile. Further, it undergoes Henry reaction to form nitroaldols by reacting with nitromethane.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Durndell, L. J.; Wilson, K.; Lee, A. F. Platinum-catalysed cinnamaldehyde hydrogenation in continuous flow. RSC Adv. 2015, 5 (97), 80022-80026.

Kashyap, B.; Phukan, P. CuI catalyzed Barbier type allylation of aldehyde in presence of S1,S2-dipyridin-2-yl ferrocene-1,1'-dicarbothioate as ligand. Indian J. Chem. 2015, 54, 662-670.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1071910
Harmonized Tariff Code
2912.29
TSCA
Yes
RTECS
MW4890000

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