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1,2-Difluorobenzene(1,2-DFB) has been used to study the mechanism of dissociation of o-, m- and p-difluorobenzene ions by threshold photoelectron photoion coincidence spectroscopy. It has been used to study the room temperature adsorption of 1,2-DFB, 1,2-dichlorobenzene and 1,2-dibromobenzene on Si(100)2x1 by X-ray photoelectron spectroscopy and temperature programmed desorption. It is used as solvent in electrochemical studies on transition metal complexes. It is also applied as a solvent useful for electrochemical studies on transition metal complexes.
Anne-Marie Boulanger, et al. Ionized o-, m-, and p-difluorobenzene dissociate through ring-opened intermediates: a TPEPICO investigation.J Am Soc Mass Spectrom.,2009,20(1), 20-4.
Zhou XJ and Leung KT. Competition between associative and dissociative adsorption of 1, 2-dihalogenated benzenes on Si (100) 2× 1: Formation of dihalocyclohexadiene, halophenyl and phenylene adstructures.Surface Science.,2006,600(16), 3285-3296.
Yang H, et al. Hydrodefluorination of fluorobenzene and 1, 2-difluorobenzene under mild conditions over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst.Organometallics.,1999,18(21), 2285-2287.
Lithiation occurs at the 3-position. For a study of lithiation under various conditions, see: J. Chem. Soc., Perkin 1, 2729 (1995).
Hazard Statements: H225-H319
Highly flammable liquid and vapour. Causes serious eye irritation.
Precautionary Statements: P210-P260-P243-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.