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367-11-3 - 1,2-Difluorobenzene, 98+% - o-Difluorobenzene - A10377 - Alfa Aesar

A10377 1,2-Difluorobenzene, 98+%

CAS Number
367-11-3
Synonyms
o-Difluorobenzene

Size Price ($) Quantity Availability
10g 41.49
50g 144.90
250g 501.60
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1,2-Difluorobenzene, 98+%

MDL
MFCD00000284
EINECS
206-680-7

Chemical Properties

Formula
C6H4F2
Formula Weight
114.09
Melting point
-34°
Boiling Point
92-94°
Flash Point
1°(33°F)
Density
1.171
Refractive Index
1.4440
Solubility
Not miscible or difficult to mix in water.

Applications

1,2-Difluorobenzene(1,2-DFB) has been used to study the mechanism of dissociation of o-, m- and p-difluorobenzene ions by threshold photoelectron photoion coincidence spectroscopy. It has been used to study the room temperature adsorption of 1,2-DFB, 1,2-dichlorobenzene and 1,2-dibromobenzene on Si(100)2x1 by X-ray photoelectron spectroscopy and temperature programmed desorption. It is used as solvent in electrochemical studies on transition metal complexes. It is also applied as a solvent useful for electrochemical studies on transition metal complexes.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep away from ignition sources. Protect against electrostatic charges.

Literature References

Anne-Marie Boulanger, et al. Ionized o-, m-, and p-difluorobenzene dissociate through ring-opened intermediates: a TPEPICO investigation.J Am Soc Mass Spectrom.,2009,20(1), 20-4.

Zhou XJ and Leung KT. Competition between associative and dissociative adsorption of 1, 2-dihalogenated benzenes on Si (100) 2× 1: Formation of dihalocyclohexadiene, halophenyl and phenylene adstructures.Surface Science.,2006,600(16), 3285-3296.

Yang H, et al. Hydrodefluorination of fluorobenzene and 1, 2-difluorobenzene under mild conditions over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst.Organometallics.,1999,18(21), 2285-2287.

Lithiation occurs at the 3-position. For a study of lithiation under various conditions, see: J. Chem. Soc., Perkin 1, 2729 (1995).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H319

Highly flammable liquid and vapour. Causes serious eye irritation.

Precautionary Statements: P210-P260-P243-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1905113
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
No
RTECS
CZ5655000

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