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A10390 2-Chlorothiophene, 98+%

CAS Number
96-43-5
Synonyms
2-Thienyl chloride

Stock No. Size Price ($) Quantity Availability
A10390-18 50g 39.40
A10390-30 250g 152.00
A10390-0B 1000g 479.00
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2-Chlorothiophene, 98+%

MDL
MFCD00005421
EINECS
202-505-3

Chemical Properties

Formula
C4H3ClS
Formula Weight
118.59
Melting point
-72°
Boiling Point
127-129°
Flash Point
22°(71°F)
Density
1.285
Refractive Index
1.5480
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

It is used in the preparation of 5-phenylthiophene derivative and N-arylhydroxamic acids.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Protect from electrostatic charges and keep away from ignition sources.

Literature References

Marc Steinmetz, et al. Mechanistic studies on the Pd-catalyzed direct C-H arylation of 2-substituted thiophene derivatives with arylpalladium bipyridyl complexes. Chem Asian J.,2012,7(6), 1256-1260.

Monali Kawade, et al. Photodissociation dynamics of halogenated thiophenes at 235 nm: a resonance enhanced multiphoton ionization-time-of-flight (REMPI-TOF) study.J Phys Chem A.,2012,116(44), 10656-10667.

K. Rama Pande, et al. Preparation and properties of N-arylhydroxamic acids.J. Chem. Eng. Data.,1979,24(1), 72-74.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H311-H331

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P311-P312-P330-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
104652
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2934.99
TSCA
Yes

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