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A10408 1,4-Cyclohexanedione monoethylene acetal, 97%

CAS Number
4746-97-8
Synonyms
1,4-Dioxaspiro[4.5]decan-8-one

Stock No. Size Price ($) Quantity Availability
A10408-06 5g 38.10
A10408-14 25g 116.00
A10408-22 100g 346.00
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1,4-Cyclohexanedione monoethylene acetal, 97%

MDL
MFCD00010214
EINECS
000-000-0

Chemical Properties

Formula
C8H12O3
Formula Weight
156.18
Melting point
72-75°
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in chloroform & methanol.

Applications

1,4-Cyclohexanedione is used in the preparation of series of potent analgesic compounds. 1,4-Cyclohexanedione is also used as a building block in the synthesis of tritium labelled probes for the autoradiography study of the dopamine reuptake complex.

Notes

Moisture Sensitive. Store away from moisture and oxidizing agents. Incompatible with strong oxidizing agents and strong acids. Ensure adequate ventilation during use.

Literature References

Chad T. Hamik; Niklas Manz; and Oliver Steinbock. Anomalous Dispersion and Attractive Pulse Interaction in the 1,4-Cyclohexanedione Belousov-Zhabotinsky Reaction. J. Phys. Chem. A. 2001, 105 (25)6144-6153.

Useful monoprotected form of the dione. For use in a 3 step synthesis of 1-azaadamantan-4-one, see: Synthesis, 1080 (1992).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
117631
Harmonized Tariff Code
2932.99
TSCA
No

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