Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

108-48-5 - 2,6-Lutidine, 98+% - 2,6-Dimethylpyridine - A10478 - Alfa Aesar

A10478 2,6-Lutidine, 98+%

CAS Number
108-48-5
Synonyms
2,6-Dimethylpyridine

Size Price ($) Quantity Availability
25ml 16.48
100ml 27.19
500ml 72.10
Add to Cart Add to Quote Request View Item

2,6-Lutidine, 98+%

MDL
MFCD00006345
EINECS
203-587-3

Chemical Properties

Formula
C7H9N
Formula Weight
107.16
Melting point
-7°
Boiling Point
143-145°
Flash Point
33°(91°F)
Density
0.923
Refractive Index
1.4970
Sensitivity
Hygroscopic
Solubility
Miscible with water.

Applications

2,6-Lutidine is used as a solvent in organic synthesis and as a sterically hindered mild base. It is also used as a vulcanization accelerator for dyes, resins and rubber. It also acts as a food additive.

Notes

Incompatible with acids, acid chlorides, oxidizing agents and chloroformates.

Literature References

This hindered base has been recommended for the exhaustive methylation of aromatic amines: J. Org. Chem., 35, 1558 (1970), and for the Rosenmund reduction of acyl halides to aldehydes: Synthesis, 767 (1976).

Base catalyst for the silylation of highly-hindered secondary or tertiary alcohols by tert-Butyl­dimethyl­silyl­ trifluoromethanesulfonate, A12174.

For monometallation with potassium amide in liquid ammonia, and subsequent carboethoxylation with diethyl carbonate, see: Org. Synth. Coll., 6, 611 (1988).

/

Timmiatia, S. N.; Jalila, A. A.; Triwahyono, S.; Setiabudi, H. D.; Annuar, N. H. R. Formation of acidic Brönsted (MoOx)-(Hy)+ evidenced by XRD and 2,6-lutidine FTIR spectroscopy for cumene cracking. Appl. Catal., A2013, 459, 8-16.

Geoghegan, K.; Bode, J. W. Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles. Org. Lett. 2015, 17 (8), 1934-1937.

Hanson, S. K.; Baker, R. T. Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts. Acc. Chem. Res. 2015,48 (7), 2037-2048.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280h-P305+P351+P338

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Merck
14,5616
Beilstein
105690
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
OK9700000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware