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495-18-1 - Benzohydroxamic acid, 98% - Benzhydroxamic acid - N-Benzoylhydroxylamine - A10509 - Alfa Aesar

A10509 Benzohydroxamic acid, 98%

CAS Number
495-18-1
Synonyms
Benzhydroxamic acid
N-Benzoylhydroxylamine

Size Price ($) Quantity Availability
10g 54.18
25g 114.33
50g 206.00
250g 885.80
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Benzohydroxamic acid, 98%

MDL
MFCD00002109
EINECS
207-797-6

Chemical Properties

Formula
C7H7NO2
Formula Weight
137.14
Melting point
ca 125° dec.
Solubility
Soluble in alcohol. Slightly soluble in ether. Insoluble in benzene.

Applications

Benzhydroxamic acid is used as precursor in the synthesis of novel mono-anionic and di-anionic hydroxamato complexes by reacting with BiPh<sub>3</sub> and Bi(O(t)Bu)<sub>3</sub>, which has anti-bacterial activity against helicobacter pylori. It is used in the photometric determination of trace amounts of vanadium in alloy steels by making mixed-ligand vanadium chelates with ammonium thiocyanate. It is also involved in the palladium catalyzed synthesis of benzisoxazolones.

Notes

Store in cool place. Incompatible with strong oxidizing agents.

Literature References

Reaction with alkynes, catalyzed by NaH in DMSO, gives 2-phenyloxazoles: Can. J. Chem., 51, 1368 (1973).

Oxidation with tetraalkylammonium periodates generates the transient benzoylnitroso compound, which can react in situ with dienes to give good yields of cycloaddition products: Tetrahedron Lett., 4763 (1978); J. Chem. Soc., Perkin 1, 883, 887 (1985); J. Org. Chem., 50, 1911 (1985).

Gibson, G. E.; Kelebek, S.; Aghamirian, M.; Yu, B. Flotation of pyrochlore from low grade carbonatite gravity tailings with benzohydroxamic acid. Miner. Eng. 2015, 71, 97-104.

Yang, S.; Feng, Q.; Qiu, X.; Gao, Y.; Xie, Z. Relationship between flotation and Fe/Mn ratio of wolframite with benzohydroxamic acid and sodium oleate as collectors. Physicochem. Probl. Miner. Process. 2014, 50 (2), 747-758.

GHS Hazard and Precautionary Statements

Hazard Statements: H341-H315-H319-H335

Suspected of causing genetic defects. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P201-P261-P280-P281-P305+P351+P338-P304+P340-P362-P312-P405-P501a

Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1907585
Harmonized Tariff Code
2924.29
TSCA
Yes
RTECS
DF9650000

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