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1,4-Dibromobenzene is used in the synthesis of 2,5-dibromoacetophenone, triarylamines and trans- stilbenes. It is widely used as a heavy liquid solvent as well as a motor oil additive. It finds application as an intermediate in the manufacture of organic chemicals such as dyes, pharmaceuticals and flame retardants for polymeric materials.
In the presence of NiCl2, cross-coupling with aryl Grignards gives p-terphenyls: Synthesis, 147 (1990).
Cano, N. H.; Ballari, M. S.; Lopez, A. G.; Santiago, A. N. New Synthesis and Biological Evaluation of Benzothiazole Derivates as Antifungal Agents. J. Agric. Food Chem. 2015, 63 (14), 3681-3686.
Vazdar, M.; Mitchell, A. S.; Warrener, R. N.; Margetic, D. High pressure promoted exchange of guests from hemicarceplexes. Tetrahedron 2015, 71 (4), 550-553.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant