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106-37-6 - 1,4-Dibromobenzene, 98% - p-Dibromobenzene - A10517 - Alfa Aesar

A10517 1,4-Dibromobenzene, 98%

CAS Number
106-37-6
Synonyms
p-Dibromobenzene

Size Price ($) Quantity Availability
50g 15.73
100g 26.39
250g 41.41
2500g 227.70
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1,4-Dibromobenzene, 98%

MDL
MFCD00000089
EINECS
203-390-2

Chemical Properties

Formula
C6H4Br2
Formula Weight
235.91
Melting point
86-90°
Boiling Point
219-220°
Flash Point
>100°(212°F)
Density
1.841
Refractive Index
1.5742
Solubility
Soluble in alcohol, benzene, chloroform, toluene and carbon tetrachloride. Insoluble in ether.

Applications

1,4-Dibromobenzene is used in the synthesis of 2,5-dibromoacetophenone, triarylamines and trans- stilbenes. It is widely used as a heavy liquid solvent as well as a motor oil additive. It finds application as an intermediate in the manufacture of organic chemicals such as dyes, pharmaceuticals and flame retardants for polymeric materials.

Notes

Avoid excessive heat and light. Incompatible with strong oxidizing agents.

Literature References

In the presence of NiCl2, cross-coupling with aryl Grignards gives p-terphenyls: Synthesis, 147 (1990).

Cano, N. H.; Ballari, M. S.; Lopez, A. G.; Santiago, A. N. New Synthesis and Biological Evaluation of Benzothiazole Derivates as Antifungal Agents. J. Agric. Food Chem. 2015, 63 (14), 3681-3686.

Vazdar, M.; Mitchell, A. S.; Warrener, R. N.; Margetic, D. High pressure promoted exchange of guests from hemicarceplexes. Tetrahedron 2015, 71 (4), 550-553.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H303-H401-H411

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Precautionary Statements: P273-P280g-P305+P351+P338

Avoid release to the environment. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Merck
14,3019
Beilstein
1904543
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CZ1791000

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