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2417-72-3 - Methyl 4-(bromomethyl)benzoate, 98% - 4-(Bromomethyl)benzoic acid methyl ester - A10557 - Alfa Aesar

A10557 Methyl 4-(bromomethyl)benzoate, 98%

CAS Number
2417-72-3
Synonyms
4-(Bromomethyl)benzoic acid methyl ester

Size Price ($) Quantity Availability
5g 36.09
25g 105.60
100g 345.60
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Methyl 4-(bromomethyl)benzoate, 98%

MDL
MFCD00032453
EINECS
000-000-0

Chemical Properties

Formula
C9H9BrO2
Formula Weight
229.07
Melting point
53-58°
Boiling Point
130-135°/2mm
Solubility
Lowly soluble in water, highly soluble in ethanol and ether, not soluble in halogenated organic solvents

Applications

Methyl 4-(bromomethyl)benzoate is used in the preparation of potential anti-HIV agents. It i s also used as a catalyst for rearrangement of benzylthiothiazoline derivatives in the preparation aldose reductase inhibitors.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air sensitive. Handle and store under inert gas. Keep away from strong oxidizing agents, strong bases. Stable under recommended storage conditions.

Literature References

HS Yathirajan, S Bindya, BK Sarojini. Methyl 4-(bromomethyl) benzoate. Acta Cryst. 1969 E63, (1) , 1334-1335.

WT Sing.; CL Lee.; SL Yeo.; SP Lim.; MM Sim. Arylalkylidene rhodanine with bulky and hydrophobic functional group as selective HCV NS3 protease inhibitor. Bioorganic & Medicinal Chemistry Letters.. 2001 11, (2) , 91-94.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1867272
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2916.39
TSCA
No

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