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A10557 Methyl 4-(bromomethyl)benzoate, 98%

CAS Number
2417-72-3
Synonyms
4-(Bromomethyl)benzoic acid methyl ester

Stock No. Size Price ($) Quantity Availability
A10557-06 5g 41.70
A10557-14 25g 129.00
A10557-22 100g 441.00
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Methyl 4-(bromomethyl)benzoate, 98%

MDL
MFCD00032453
EINECS
000-000-0

Chemical Properties

Formula
C9H9BrO2
Formula Weight
229.07
Melting point
53-58°
Boiling Point
130-135°/2mm
Storage & Sensitivity
Ambient temperatures.
Solubility
Lowly soluble in water, highly soluble in ethanol and ether, not soluble in halogenated organic solvents

Applications

Methyl 4-(bromomethyl)benzoate is used in the preparation of potential anti-HIV agents. It i s also used as a catalyst for rearrangement of benzylthiothiazoline derivatives in the preparation aldose reductase inhibitors.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air sensitive. Handle and store under inert gas. Keep away from strong oxidizing agents, strong bases. Stable under recommended storage conditions.

Literature References

HS Yathirajan, S Bindya, BK Sarojini. Methyl 4-(bromomethyl) benzoate. Acta Cryst. 1969 E63, (1) , 1334-1335.

WT Sing.; CL Lee.; SL Yeo.; SP Lim.; MM Sim. Arylalkylidene rhodanine with bulky and hydrophobic functional group as selective HCV NS3 protease inhibitor. Bioorganic & Medicinal Chemistry Letters.. 2001 11, (2) , 91-94.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H314-H334-H335

Harmful if swallowed. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P270-P271-P280-P285-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1867272
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2916.39
TSCA
No

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