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A10575 Tetraphenylphosphonium chloride, 98%

CAS Number
2001-45-8
Synonyms

Stock No. Size Price ($) Quantity Availability
A10575-04 2g 24.30
A10575-09 10g 83.60
A10575-18 50g 268.00
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Tetraphenylphosphonium chloride, 98%

MDL
MFCD00011916
EINECS
217-890-3

Chemical Properties

Formula
(C6H5)4PCl
Formula Weight
374.86
Melting point
272-278°
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water.

Applications

Tetraphenylphosphonium chloride is used to generate lipophilic salts from inorganic and organometallic anions. Thus, Ph4P+ is useful as a phase-transfer catalyst, again because it allows inorganic anions to dissolve in organic solvents.

Notes

It is hygroscopic. Incompatible with oxidizing agents.

Literature References

David R.Wood; Fred W.Reimherr; Paul H.Wender. Mechanism of inhibition of fadu hypopharyngeal carcinoma cell growth by tetraphenylphosphonium chloride. International Journal of Cancer. 1994, 57, (2),247-253

 

J.T.van Elteren; N.G.Haselager; H.A.Das C.L. de Ligny; J.Agterdenbos. Determination of arsenate in aqueous samples by precipitation of the arsenic(V)—molybdate complex with tetraphenylphosphonium chloride and neutron activation analysis or hydride generation atomic absorption spectrometry. Analytica Chimica Acta. 1991, 252, (1-2),89-95

Reagent for Bi and Co.

High-temperature phase-transfer catalyst (see Appendix 2). In combination with Bis(acetonitrile)­dichloropalladium(II)­, 10002, provides an effective catalyst for the Heck reaction of normally unreactive aryl halides, e.g. chlorobenzene with styrene to give stilbene. The reaction is performed at 140-150o in DMF or NMP in the presence of sodium acetate. The reaction may be further improved by the addition of 10-12 mol% N,N-Dimethyl­glycine, A19670: Angew. Chem. Int. Ed., 37, 481 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3922393
Harmonized Tariff Code
2931.39
TSCA
No

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