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96-32-2 - Methyl bromoacetate, 98+% - Bromoacetic acid methyl ester - A10605 - Alfa Aesar

A10605 Methyl bromoacetate, 98+%

CAS Number
96-32-2
Synonyms
Bromoacetic acid methyl ester

Size Price ($) Quantity Availability
50g 35.43
250g 95.69
1000g 284.28
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Methyl bromoacetate, 98+%

MDL
MFCD00000189
EINECS
202-499-2

Chemical Properties

Formula
C3H5BrO2
Formula Weight
152.98
Melting point
-50°
Boiling Point
144-145°
Flash Point
62°(143°F)
Density
1.655
Refractive Index
1.4585
Solubility
Miscible with methanol, ether and acetone. Slightly miscible with water

Applications

Methyl bromoacetate is used in the synthesis of coumarins and cis-cyclopropanes. It reacts with the conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) to prepare alkylated carbene complexes. Further, it is used to make vitamins and pharmaceuticals.

Notes

Incompatible with acids, bases, oxidizing agents and reducing agents.

Literature References

Dib, J.; Schlörer, N.; Schänzer, W.; Thevis, M. Studies on the collision-induced dissociation of adipoR agonists after electrospray ionization and their implementation in sports drug testing. J. Mass Spectrom. 2015, 50 (2), 407-417.

Hoashi, Y.; Takai, T.; Koike, T.; Uchikawa, O. Synthesis of a novel tricyclic 1, 6, 7, 8-tetrahydro-2H-cyclopenta [b] furo [3, 2-d] pyridine derivative, the 5-aza analog of ramelteon. Tetrahedron Lett. 2014, 55 (29), 4014-4016.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H314-H318-H227

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Precautionary Statements: P210-P260-P261-P301+P310-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
506256
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes
RTECS
AF6300000

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