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A10681 2-Buten-1-ol, cis + trans (ca 1:19), 96%

CAS Number
6117-91-5
Synonyms
Crotyl alcohol
1-Hydroxybut-2-ene

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Bulk/Specialty

2-Buten-1-ol, cis + trans (ca 1:19), 96%

MDL
MFCD00002923
EINECS
228-086-7

Chemical Properties

Formula
CH3CH=CHCH2OH
Formula Weight
72.11
Boiling Point
121-122°
Flash Point
37°(98°F)
Density
0.848
Refractive Index
1.4280
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water.

Applications

2-Buten-1-ol, cis + trans (ca 1:19) is used as a building block for the synthesis of various pharmaceutical compounds such as crotyl mercaptan.

Notes

Incompatible with strong acids, strong oxidizing agents, strong reducing agents, acid chlorides, acid anhydrides and phosphorus halides.

Literature References

Meunier, F. C.; Scalbert, J.; Thibault-Starzyk, F. Unraveling the mechanism of catalytic reactions through combined kinetic and thermodynamic analyses: Application to the condensation of ethanol. C.R. Chim. 2015, 18 (3), 345-350.

Di Pietrantonio, K.; Coccia, F.; Tonucci, L.; d'Alessandro, N.; Bressan, M. Hydrogenation of allyl alcohols catalyzed by aqueous palladium and platinum nanoparticles.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H312-H315-H319-H332-H335

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2601
Beilstein
1719374
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.29
TSCA
Yes
RTECS
EM9275000

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