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A10696 1-Bromobutane, 98+%

CAS Number
109-65-9
Synonyms
n-Butyl bromide

SDS Certificate of Analysis Product Specification Technical Inquiry
Stock No. Size Price ($) Quantity Availability
A10696-36 500g 37.70
A10696-0E 2500g 108.00
A10696-0C 10000g 323.00
Add to Cart Bulk/Specialty Print Quote View Item

1-Bromobutane, 98+%

MDL
MFCD00000260
EINECS
203-691-9

Chemical Properties

Formula
C4H9Br
Formula Weight
137.03
Melting point
-112°
Boiling Point
101-102°
Flash Point
20°(68°F)
Density
1.275
Refractive Index
1.4400
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with ethanol and diethyl ether. Immiscible with water.

Applications

1-Bromobutane is used as an intermediate in organic synthesis and as a solvent for cleaning and degreasing. It acts as an alkylating agent as well as to prepare organometallic compounds such as n-butyllithium. It is also involved in the synthesis of procaine and tetracaine. It reacts with magnesium metal to prepare the Grignard reagent, which is used to form carbon-carbon bonds.

Notes
Incompatible with strong oxidizing agents, strong bases, magnesium, potassium, sodium and sodium oxides.

Literature References

Chief Elk, J.; Benjamin, I. beta-Cyclodextrin at the water/1-bromobutane interface: molecular insight into reverse phase transfer catalysis. Langmuir 2015, 31 (18), 5086-5092.

Paulechka, Y. U.; Kabo, G. J.; Blokhin, A. V.; Firaha, D. S. Thermodynamics of ionic liquid precursors. 1-Bromobutane and its isomers.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P264b-P280-P303+P361+P353-P305+P351+P338-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1553
Beilstein
1098260
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
EJ6225000

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