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51437-00-4 - 5-Bromo-2-fluorotoluene, 98+% - A10721 - Alfa Aesar

A10721 5-Bromo-2-fluorotoluene, 98+%

CAS Number
51437-00-4
Synonyms

Size Price ($) Quantity Availability
5g 32.22
25g 107.75
100g 432.60
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5-Bromo-2-fluorotoluene, 98+%

MDL
MFCD00000343
EINECS
257-202-9

Chemical Properties

Formula
C7H6BrF
Formula Weight
189.03
Boiling Point
94-95°/50mm
Flash Point
73°(163°F)
Density
1.486
Refractive Index
1.5290
Solubility
Not miscible or difficult to mix in water.

Applications

5-Bromo-2-fluorotoluene is used in the preparation of 5-bromo-2-fluorobenzyl bromide via N-bromosuccinimide (NBS) bromination, required for the synthesis of crown bromofluorobenzene and 3-(4-fuoro-3-methylphenyl)acrylamide. It is also used as an intermediates of medicine.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

M. Sletzinger.; T.R. Verhoeven.; R.P. Volante.; J.M. McNamara.; E.G. Corley.; T.M.H. Liu. A diastereospecific, non-racemic synthesis of a novel β-hydroxy-δ-lactone HMG-CoA reductase inhibitor. Tetrahedron Letters. 1985, 26, (25), 2951-2954.

Praew Thansandote.; Eugene Chong.; Kai-Oliver Feldmann.; Mark Lautens. Palladium-Catalyzed Domino C-C/C-N Coupling Using a Norbornene Template: Synthesis of Substituted Benzomorpholines, Phenoxazines, and Dihydrodibenzoxazepines. J. Org. Chem. 2010, 75 (10), 3495-3498.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2242693
Harmonized Tariff Code
2903.99
TSCA
No

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