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1745-81-9 - 2-Allylphenol, 98+% - A10755 - Alfa Aesar

A10755 2-Allylphenol, 98+%

CAS Number
1745-81-9
Synonyms

Size Price ($) Quantity Availability
100g 32.13
500g 103.05
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2-Allylphenol, 98+%

MDL
MFCD00002250
EINECS
217-119-0

Chemical Properties

Formula
C9H10O
Formula Weight
134.18
Melting point
-6°
Boiling Point
220-222°
Flash Point
88°(190°F)
Density
1.024
Refractive Index
1.5450
Solubility
Soluble in water(7 g/L).

Applications

2-Allylphenol is an protected intermediate in the synthesis of metabolites of Diclofenac (D436450), a nonsteroidal anti-inflammatory compound an decycloxygenase (COX) inhibitor.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and bases.

Literature References

Daniele Reyx; Irene Campistron; Christophe Caillaud; Martine Villatte; Annick Cavedon. Thermal reaction between N-phenylmaleimide and 2-allylphenol as a model for the crosslinking reaction in bismaleimide polymerization with diallylbisphenol A. Macromolecular Chemistry and Physics. 1995, 196, (3),775-785

 

Ted Schaefer; Rudy Sebastian; Timothy A.Wildman. The allyl and benzyl groups as hydrogen bond acceptors in derivatives of 2-allylphenol and 2-benzylphenol. Canadian Journal of Chemistry. 1979, 57, (22),3005-3009

Undergoes phosphine-free Pd-catalyzed cross-coupling with vinylic halides and triflates to give dihydrobenzopyrans: Tetrahedron Lett., 39, 237 (1998); for reaction scheme, see Palladium(II)­ acetate, 10516.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H314-H318-H227

Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Precautionary Statements: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
742121
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2907.19
TSCA
Yes
RTECS
SJ3850000

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