Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

127-06-0 - Acetone oxime, 98% - Acetoxime - 2-Propanone oxime - A10802 - Alfa Aesar

A10802 Acetone oxime, 98%

CAS Number
127-06-0
Synonyms
Acetoxime
2-Propanone oxime

Size Price ($) Quantity Availability
50g 18.32
250g 60.93
1000g 207.00
Add to Cart Add to Quote Request View Item

Acetone oxime, 98%

MDL
MFCD00002118
EINECS
204-820-1

Chemical Properties

Formula
C3H7NO
Formula Weight
73.10
Melting point
60-63°
Boiling Point
133-135°
Flash Point
60°(140°F)
Density
0.901
Solubility
Soluble in water (330 g/L at 20°C).

Applications

It is an intermediate used in organic synthesis and in agriculture. It is also an important raw material.

Notes

Store away from oxidizing agents. Protect against electrostatic charges.

Literature References

Jianjun Wu.; Sarah C. Larsen. Solid-State Nuclear Magnetic Resonance Study of Acetone Oxime Adsorbed on CuZSM-5 and on HZSM-5. Journal of Catalysis. 1999, 182, (1), 244-256.

Karl Sohlberg.; Scott P. Leary.; Noel L. Owen.; Boris A. Trofimov. The infrared spectrum and conformation of acetone oxime vinyl ether. Vibrational Spectroscopy. 1997, 13, (2), 227-234.

Aldehydes and ketones can be converted to their oximes in high yield by an exchange process involving heating with acetone oxime in acetic acid at 110o: J. Prakt. Chem., 331, 870 (1989).

N-Protected form of hydroxylamine. For O-alkylation with sodium bromoacetate, and acid hydrolysis to O-carboxymethylhydroxylamine hydrochloride, see: Org. Synth. Coll., 3, 172 (1955).

For use of this and other simple oximes in the formation, by DCC-coupling, of active esters of N-protected oligopeptides, which react with C-protected amino acids to give peptides in high yield, see: Chem. Pharm. Bull., 17, 2937 (1969). See Appendix 6.

GHS Hazard and Precautionary Statements

Hazard Statements: H228

Flammable solid.

Precautionary Statements: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Other References

Merck
14,75
Beilstein
1560146
Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AL6825000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware