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A10802 Acetone oxime, 98%

CAS Number
127-06-0
Synonyms
Acetoxime
2-Propanone oxime

Stock No. Size Price ($) Quantity Availability
A10802-18 50g 23.40
A10802-30 250g 63.50
A10802-0B 1000g 230.00
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Acetone oxime, 98%

MDL
MFCD00002118
EINECS
204-820-1

Chemical Properties

Formula
C3H7NO
Formula Weight
73.10
Melting point
60-63°
Boiling Point
133-135°
Flash Point
60°(140°F)
Density
0.901
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (330 g/L at 20°C).

Applications

It is an intermediate used in organic synthesis and in agriculture. It is also an important raw material.

Notes

Store away from oxidizing agents. Protect against electrostatic charges.

Literature References

Jianjun Wu.; Sarah C. Larsen. Solid-State Nuclear Magnetic Resonance Study of Acetone Oxime Adsorbed on CuZSM-5 and on HZSM-5. Journal of Catalysis. 1999, 182, (1), 244-256.

Karl Sohlberg.; Scott P. Leary.; Noel L. Owen.; Boris A. Trofimov. The infrared spectrum and conformation of acetone oxime vinyl ether. Vibrational Spectroscopy. 1997, 13, (2), 227-234.

Aldehydes and ketones can be converted to their oximes in high yield by an exchange process involving heating with acetone oxime in acetic acid at 110o: J. Prakt. Chem., 331, 870 (1989).

N-Protected form of hydroxylamine. For O-alkylation with sodium bromoacetate, and acid hydrolysis to O-carboxymethylhydroxylamine hydrochloride, see: Org. Synth. Coll., 3, 172 (1955).

For use of this and other simple oximes in the formation, by DCC-coupling, of active esters of N-protected oligopeptides, which react with C-protected amino acids to give peptides in high yield, see: Chem. Pharm. Bull., 17, 2937 (1969). See Appendix 6.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H318-H373

Flammable solid. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P240-P241-P260-P280-P305+P351+P338-P310-P314-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Get medical advice/attention if you feel unwell. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,75
Beilstein
1560146
Hazard Class
4.1
Packing Group
II
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AL6825000

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