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536-90-3 - m-Anisidine, 98% - 3-Aminoanisole - 3-Methoxyaniline - A10815 - Alfa Aesar

A10815 m-Anisidine, 98%

CAS Number
536-90-3
Synonyms
3-Aminoanisole
3-Methoxyaniline

Size Price ($) Quantity Availability
50g 30.68
250g 102.60
1000g 259.20
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m-Anisidine, 98%

MDL
MFCD00007783
EINECS
208-651-4

Chemical Properties

Formula
C7H9NO
Formula Weight
123.16
Melting point
-1°
Boiling Point
250-251°
Flash Point
126°(258°F)
Density
1.101
Refractive Index
1.5810
Sensitivity
Light Sensitive
Solubility
Soluble in water(18g/L).

Applications

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Notes

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

W. Preston Reeves,; Rufus M. King . A Convenient Method for Bromination of Aromatic Amines. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 1993, 23 (6), 855-859.

Renuka K,; RowTNG,; Prasad BR,; Subramanian CK,;Bhattacharya, S .Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials - Evidence For The Control Of 2nd-Harmonic Generation Activities From The X-Ray Crystal-Structures Of The Complexes Of L-Tartaric Acid With M-Anisidine and P-Toluidine . Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials. 1995, 19 (1), 83-89..

GHS Hazard and Precautionary Statements

Hazard Statements: H400-H410-H302-H315-H319-H335

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P273-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,667
Beilstein
386119
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2922.29
TSCA
Yes
RTECS
BZ5408000

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