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A10821 1-Bromopentane, 99%

CAS Number
110-53-2
Synonyms
n-Amyl bromide
n-Pentyl bromide

Stock No. Size Price ($) Quantity Availability
A10821-30 250g 30.00
A10821-0B 1000g 85.70
A10821-0I 5000g 375.00
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1-Bromopentane, 99%

MDL
MFCD00000267
EINECS
203-776-0

Chemical Properties

Formula
CH3(CH2)4Br
Formula Weight
151.05
Melting point
-95°
Boiling Point
127-129°
Flash Point
31°(87°F)
Density
1.215
Refractive Index
1.4436
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water and soluble in alcohol. Miscible in diethyl ether.

Applications

1-Bromopentane is used in a multitude of organic synthesis. It is used in iron-catalyzed alkylations of aromatic Grignard reagents via cross coupling.

Notes

Store away from oxidizing agents and bases.

Literature References

Keiichi Ohno.; Hiroshi Yoshida.; Hiroatsu Matsuura. Conformational dependence of the isolated C-D stretching and CHD rocking vibrations of selectively monodeuterated alkyl chains as proved by conformational polymorphism of 1-bromopentane. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 1996, 52 (11), 1377-1389.

John P. Idouxa.; Ronald Wysockia.; Sherre Younga.; Jeffrey Turcota.; Charlene Ohlmana.; Russell Leonard. Polymer-Supported “Multi-Site” Phase Transfer Catalysts. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 1983, 13 (2), 139-144.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P337+P313-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If eye irritation persists: Get medical advice/attention. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,602
Beilstein
1730981
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
RZ9770000

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