Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A10847 2-Picoline, 98+%

CAS Number
109-06-8
Synonyms
2-Methylpyridine

Stock No. Size Price ($) Quantity Availability
A10847-AE 100ml 17.70
A10847-AP 500ml 30.90
A10847-0F 2500ml 102.00
Add to Cart Bulk/Specialty Print Quote View Item

2-Picoline, 98+%

MDL
MFCD00006332
EINECS
203-643-7

Chemical Properties

Formula
C6H7N
Formula Weight
93.13
Melting point
-70°
Boiling Point
128-129°
Flash Point
26°(78°F)
Density
0.944
Refractive Index
1.5000
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water.

Applications

2-Picoline is used as an intermediate in agrochemicals and pharmaceuticals. It serves as a solvent as well as to prepare dyes and resins. It finds application as a constituent in cigarette smoke, bone oil, coal tar and coke oven emissions. Further, it acts as a precursor of 2-vinylpyridine, picolinic acid and nitrapyrin. It is also employed to study the electron and proton transfer reactions of lumiflavin. In addition, it is used in the synthetic pathway for the preparation of dearomatized, allylated and carbon-hydrogen bond activated pyridine derivatives.

Notes

Hygroscopic. Incompatible with strong oxidizing agents, sulfuric acid, acids, metals, iron(II) sulfate and hydrogen peroxide.

Literature References

Dhau, J. S.; Singh, A. A study on the BF3-directed lithiation of 2-picoline and 2,3-lutidine. J. Organomet. Chem. 2014, 749, 109-114.

Li, B.; Wei, H.; Li, H.; Pereshivko, O. P.; Peshkov, V. A. Direct addition of 2-methylazines to aryl glyoxals for the synthesis of alpha-hydroxy ketones. Tetrahedron Lett. 2015, 56 (37), 5231-5234.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H311-H319-H332-H335

Flammable liquid and vapour. Harmful if swallowed. Toxic in contact with skin. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7400
Beilstein
104581
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
TJ4900000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware