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4-Bromo-N,N-dimethylaniline is used as an internal standard in the determination of iodine present as iodide (as in pharmaceuticals), iodate (as in iodized table salt) and covalently bound to organic compounds (as in milk and vegetables).
Vincent Paul.; A. Sudalai.; Thomas Daniel.; K.V. Srinivasan. Regioselective bromination of activated aromatic substrates with N-bromosuccinimide over HZSM-5. Tetrahedron Letters. 1994, 35, (38), 7055-7056.
Paramita Das.; Manju Gupta.; Archana Jain.; Krishna K. Verma. Single drop microextraction or solid phase microextraction-gas chromatography-mass spectrometry for the determination of iodine in pharmaceuticals, iodized salt, milk powder and vegetables involving conversion into 4-iodo-N,N-dimethylaniline. Journal of Chromatography A. 2004, 1023, (1), 33-39.
Hazard Statements: H302-H312-H331-H315-H319
Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.