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699-12-7 - 2-(Phenylthio)ethanol, 99% - 2-Hydroxyethyl phenyl sulfide - A10861 - Alfa Aesar

A10861 2-(Phenylthio)ethanol, 99%

CAS Number
699-12-7
Synonyms
2-Hydroxyethyl phenyl sulfide

Size Price ($) Quantity Availability
10g 22.45
50g 59.94
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2-(Phenylthio)ethanol, 99%

MDL
MFCD00002905
EINECS
211-828-9

Chemical Properties

Formula
C6H5S(CH2)2OH
Formula Weight
154.23
Boiling Point
115-116°/2mm
Flash Point
>110°(230°F)
Density
1.147
Refractive Index
1.5920

Literature References

Reagent for phosphate protection in oligonucleotide synthesis. The resulting esters are stable to base, sulfonylation, and to mild acid, but can be deprotected by periodate oxidation to the sulfoxide: Can. J. Chem., 50, 456, 769 (1972), or NCS oxidation to the sulfone: J. Am. Chem. Soc., 95, 2020 (1973), either of which can then be cleaved by base-induced elimination. For use in pyrimidine protection of thymidine analogs, via Mitsunobu N-alkylation, m-CPBA oxidation to the sulfone and cleavage with dilute NaOH, see: Synlett, 845 (2006).

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Other References

Beilstein
1860057
Harmonized Tariff Code
2930.90
TSCA
Yes

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