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A10861 2-(Phenylthio)ethanol, 99%

CAS Number
699-12-7
Synonyms
2-Hydroxyethyl phenyl sulfide

Stock No. Size Price ($) Quantity Availability
A10861-09 10g 22.20
A10861-18 50g 67.90
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2-(Phenylthio)ethanol, 99%

MDL
MFCD00002905
EINECS
211-828-9

Chemical Properties

Formula
C6H5S(CH2)2OH
Formula Weight
154.23
Boiling Point
115-116°/2mm
Flash Point
>110°(230°F)
Density
1.147
Refractive Index
1.5920
Storage & Sensitivity
Ambient temperatures.

Literature References

Reagent for phosphate protection in oligonucleotide synthesis. The resulting esters are stable to base, sulfonylation, and to mild acid, but can be deprotected by periodate oxidation to the sulfoxide: Can. J. Chem., 50, 456, 769 (1972), or NCS oxidation to the sulfone: J. Am. Chem. Soc., 95, 2020 (1973), either of which can then be cleaved by base-induced elimination. For use in pyrimidine protection of thymidine analogs, via Mitsunobu N-alkylation, m-CPBA oxidation to the sulfone and cleavage with dilute NaOH, see: Synlett, 845 (2006).

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GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1860057
Harmonized Tariff Code
2930.90
TSCA
Yes

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