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612-24-8 - 2-Nitrobenzonitrile, 98+% - 2-Cyanonitrobenzene - A10941 - Alfa Aesar

A10941 2-Nitrobenzonitrile, 98+%

CAS Number
612-24-8
Synonyms
2-Cyanonitrobenzene

Size Price ($) Quantity Availability
5g 30.78
25g 101.04
100g 275.20
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2-Nitrobenzonitrile, 98+%

MDL
MFCD00007044
EINECS
210-301-0

Chemical Properties

Formula
C7H4N2O2
Formula Weight
148.12
Melting point
107-111°
Boiling Point
165°/16mm
Solubility
Insoluble in water.

Applications

ET catalysis of Au25 in intramolecular cascade reaction of 2-nitrobenzonitrile, from which 2-amniobenzamide (a precursor of significant pharmaceuticals20,21) is produced with high yield. fluorodenitration of 2-nitrobenzonitrile with Rb18F in DMSO gave an 85% yield of the 18F-labelled benzonitrile after only 20 minutes at 150°C.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Hanbao Chong,; Peng Li,; Shuxin Wang,; Fangyu Fu,; Ji Xiang,; Manzhou Zhu,; Yadong Li. Au25 Clusters as Electron-Transfer Catalysts Induced the Intramolecular Cascade Reaction of 2-nitrobenzonitrile. Scientific Reports. 2013 , 3

Klara Koprivova,; Libor Cerveny. Hydrogenation of nitrobenzonitriles using Raney nickel catalyst. : Research on Chemical Intermediates. 2008, 34 (1), 93.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H311

Fatal if swallowed. Toxic in contact with skin.

Precautionary Statements: P280h-P309-P310-P302+P352

Wear protective gloves/clothing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
638987
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
DI4903000

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