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A10969 Acetic hydrazide, 96%

CAS Number
1068-57-1
Synonyms
Acethydrazide
Acetylhydrazine

Stock No. Size Price ($) Quantity Availability
A10969-14 25g 50.00
A10969-22 100g 148.00
A10969-36 500g 499.00
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Acetic hydrazide, 96%

MDL
MFCD00007610
EINECS
213-948-7

Chemical Properties

Formula
CH3CONHNH2
Formula Weight
74.08
Melting point
ca 60-68°
Boiling Point
128-129°/18mm
Flash Point
>110°(230°F)
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in water.

Applications

Acetic hydrazide is used as an antibiotic for the treatment of mycobacterium tuberculosis. It is also involved in the preparation of sunitinib b reacting with 5-fluoroisatin. Further, it inhibits mycolic acid biosynthesis. It serves as an important intermediate in organic synthesis such as nitric furosemide Long (nifuratrone) in medicine.

Notes

Hygroscopic. Incompatible with strong bases.

Literature References

Sadhukhan, D.; Maiti, M.; Pilet, G.; Bauzá, A.; Frontera, A.; Mitra, S. Hydrogen Bond, pi-pi, and CH-pi Interactions Governing the Supramolecular Assembly of Some Hydrazone Ligands and Their MnII Complexes - Structural and Theoretical Interpretation. Eur. J. Inorg. Chem. 2015, 2015 (11), 1958-1972.

Sadhukhan, D.; Maiti, M.; Zangrando, E.; Pathan, S.; Mitra, S.; Patel, A. Heterogeneous catalytic oxidation of styrene by an oxo bridged divanadium(V) complex of an acetohydrazide-Schiff base. Polyhedron 2014, 69, 1-9.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H302-H315-H319-H332-H335

Flammable solid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P240-P241-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
506165
Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AI1225000

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