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1068-57-1 - Acetic hydrazide, 96% - Acethydrazide - Acetylhydrazine - A10969 - Alfa Aesar

A10969 Acetic hydrazide, 96%

CAS Number
1068-57-1
Synonyms
Acethydrazide
Acetylhydrazine

Size Price ($) Quantity Availability
25g 49.44
100g 136.35
500g 405.26
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Acetic hydrazide, 96%

MDL
MFCD00007610
EINECS
213-948-7

Chemical Properties

Formula
CH3CONHNH2
Formula Weight
74.08
Melting point
ca 60-68°
Boiling Point
128-129°/18mm
Flash Point
>110°(230°F)
Sensitivity
Hygroscopic
Solubility
Soluble in water.

Applications

Acetic hydrazide is used as an antibiotic for the treatment of mycobacterium tuberculosis. It is also involved in the preparation of sunitinib b reacting with 5-fluoroisatin. Further, it inhibits mycolic acid biosynthesis. It serves as an important intermediate in organic synthesis such as nitric furosemide Long (nifuratrone) in medicine.

Notes

Hygroscopic. Incompatible with strong bases.

Literature References

Sadhukhan, D.; Maiti, M.; Pilet, G.; Bauzá, A.; Frontera, A.; Mitra, S. Hydrogen Bond, pi-pi, and CH-pi Interactions Governing the Supramolecular Assembly of Some Hydrazone Ligands and Their MnII Complexes - Structural and Theoretical Interpretation. Eur. J. Inorg. Chem. 2015, 2015 (11), 1958-1972.

Sadhukhan, D.; Maiti, M.; Zangrando, E.; Pathan, S.; Mitra, S.; Patel, A. Heterogeneous catalytic oxidation of styrene by an oxo bridged divanadium(V) complex of an acetohydrazide-Schiff base. Polyhedron 2014, 69, 1-9.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
506165
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AI1225000

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