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A11032 Chloroiodomethane, 98%, stab. with copper

CAS Number
593-71-5
Synonyms
Methylene chloroiodide

Stock No. Size Price ($) Quantity Availability
A11032-09 10g 38.10
A11032-18 50g 123.00
A11032-30 250g 468.00
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Chloroiodomethane, 98%, stab. with copper

MDL
MFCD00001078
EINECS
209-804-8

Chemical Properties

Formula
ClCH2I
Formula Weight
176.38
Boiling Point
108-109°
Flash Point
None
Density
2.416
Refractive Index
1.5822
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Miscible with acetone, benzene, diethyl ether and alcohol.

Applications

Chloroiodomethane is used as an intermediate in pharmaceuticals, organic synthesis, agrochemicals and dyestuff. It is also useful in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation and in epoxidation.

Notes

It is incompatible with strong oxidizing agents and strong bases.

Literature References

Degennaro, L.; Fanelli, F.; Giovine, A.; Luisi, R. External Trapping of Halomethyllithium Enabled by Flow Microreactors. Adv. Synth. Catal. 2015, 357 (1), 21-27.

Ooki, A.; Nomura, D.; Nishino, S.; Kikuchi, T.; Yokouchi, Y. A global-scale map of isoprene and volatile organic iodine in surface seawater of the Arctic, Northwest Pacific, Indian, and Southern Oceans. J. Geophys. Res. Oceans 2015, 120 (6), 4108-4128.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1730802
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2903.79
TSCA
No

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