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593-71-5 - Chloroiodomethane, 98%, stab. with copper - Methylene chloroiodide - A11032 - Alfa Aesar

A11032 Chloroiodomethane, 98%, stab. with copper

CAS Number
593-71-5
Synonyms
Methylene chloroiodide

Size Price ($) Quantity Availability
10g 36.30
50g 117.00
250g 445.00
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Chloroiodomethane, 98%, stab. with copper

MDL
MFCD00001078
EINECS
209-804-8

Chemical Properties

Formula
ClCH2I
Formula Weight
176.38
Boiling Point
108-109°
Flash Point
None
Density
2.416
Refractive Index
1.5822
Sensitivity
Light Sensitive
Solubility
Miscible with acetone, benzene, diethyl ether and alcohol.

Applications

Chloroiodomethane is used as an intermediate in pharmaceuticals, organic synthesis, agrochemicals and dyestuff. It is also useful in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation and in epoxidation.

Notes

It is incompatible with strong oxidizing agents and strong bases.

Literature References

Degennaro, L.; Fanelli, F.; Giovine, A.; Luisi, R. External Trapping of Halomethyllithium Enabled by Flow Microreactors. Adv. Synth. Catal. 2015, 357 (1), 21-27.

Ooki, A.; Nomura, D.; Nishino, S.; Kikuchi, T.; Yokouchi, Y. A global-scale map of isoprene and volatile organic iodine in surface seawater of the Arctic, Northwest Pacific, Indian, and Southern Oceans. J. Geophys. Res. Oceans 2015, 120 (6), 4108-4128.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1730802
Harmonized Tariff Code
2903.79
TSCA
No

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