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A11033 Diethylenetriamine, 99%

CAS Number
111-40-0
Synonyms
N-(2-Aminoethyl)-1,2-ethanediamine

Stock No. Size Price ($) Quantity Availability
A11033-AE 100ml 26.10
A11033-AP 500ml 29.40
A11033-0F 2500ml 71.00
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Diethylenetriamine, 99%

MDL
MFCD00008171
EINECS
203-865-4

Chemical Properties

Formula
C4H13N3
Formula Weight
103.17
Melting point
-40°
Boiling Point
200-204°
Flash Point
94°(201°F)
Density
0.952
Refractive Index
1.4830
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Miscible with water and ethanol. Immiscible with ether.

Applications

Diethylenetriamine is used as a solvent for plastics, dyes and in chemical synthesis. It serves as a curing agent for epoxy-resins. As a tridentate ligand, it form complexes such as Co(dien)(NO2)3 in coordination chemistry. It is also used as a fuel additive. It reacts with fatty acid resulting in the formation of amidoamines, which are used as corrosion inhibitors in the petroleum industry. It is associated with unsymmetrical dimethylhydrazine to prepare hydyne, which is a propellant for liquid-fuel rockets.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong acids and copper.

Literature References

Galhoum, A. A.; Mahfouz, M. G.; Rehem, S. T. A.; Gomaa, N. A.; Atia, A. A.; Vincent, T.; Guibal, E. Diethylenetriamine-functionalized chitosan magnetic nano-based particles for the sorption of rare earth metal ions [Nd(III), Dy(III) and Yb(III)]. Cellulose 2015, 22 (4), 2589-2605.

Koizumi, Y.; Hirooka, M.; Ochi, H.; Tokumoto, Y.; Takechi, M.; Hiraoka, A.; Ikeda, Y.; Kumagi, T.; Matsuura, B. Characterization of the biliary tract by virtual ultrasonography constructed by gadolinium ethoxybenzyl diethylenetriamine pentaacetic acid-enhanced magnetic resonance imaging. J Med Ultrason 2015, 42 (2), 185-193.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302+H312-H314-H317-H330-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Fatal if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P272-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
605314
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2921.29
TSCA
Yes
RTECS
IE1225000

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