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504-02-9 - 1,3-Cyclohexanedione, 97+%, may cont. up to 1% NaCl - Dihydroresorcinol - A11109 - Alfa Aesar

A11109 1,3-Cyclohexanedione, 97+%, may cont. up to 1% NaCl

CAS Number
504-02-9
Synonyms
Dihydroresorcinol

Size Price ($) Quantity Availability
25g 17.37
50g 21.12
100g 42.13
1000g 243.00
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1,3-Cyclohexanedione, 97+%, may cont. up to 1% NaCl

MDL
MFCD00001585
EINECS
207-980-0

Chemical Properties

Formula
C6H8O2
Formula Weight
112.13
Melting point
101-105°
Density
1.100
Solubility
Soluble in water (155 g/L) at 20°C, alcohol, chloroform, acetone, boiling benzene, ether (slightly), carbon disulfide (slightly), and petr ether (slightly).

Applications

It is used as a nitisinone intermediate.

Notes

Air & Light Sensitive. Store in cool, dry conditions in well sealed containers. Store away from strong oxidizing agents. Keep container tightly closed.

Literature References

Biswanath Das,; Ponnaboina Thirupathi,; K. Ravinder Reddy,; B. Ravikanth,; Lingaiah Nagarapu.1,3-Cyclohexanedione, 97+%, may cont. up to 1% NaCl. Catalysis Communications.2007 , 8 (3),535-538.

authors. title . Journal name. year of publication , volume issue , pg no.

For procedures for the conversion to the mono- and bis-silyl enol ethers, using HMDS/ imidazole and LDA/ TMS chloride respectively, see: Synthesis, 431 (1977).

Reacts with primary amines to give ß-amino enones, which can be aromatized to m-amino-phenols by oxidation with Hg(OAc)2: Synthesis, 471 (1982).

GHS Hazard and Precautionary Statements

Hazard Statements: H302

Harmful if swallowed.

Precautionary Statements: P264-P270-P301+P312-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3178
Beilstein
385888
Harmonized Tariff Code
2914.29
TSCA
Yes

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