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120-14-9 - Veratraldehyde, 99% - 3,4-Dimethoxybenzaldehyde - A11110 - Alfa Aesar

A11110 Veratraldehyde, 99%

CAS Number
120-14-9
Synonyms
3,4-Dimethoxybenzaldehyde

Size Price ($) Quantity Availability
100g 25.47
500g 75.70
2500g 254.12
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Veratraldehyde, 99%

MDL
MFCD00003363
EINECS
204-373-2

Chemical Properties

Formula
C9H10O3
Formula Weight
166.18
Melting point
42-46°
Boiling Point
281°
Flash Point
112°(233°F)
Sensitivity
Air Sensitive
Solubility
Soluble in water. Freely soluble in alcohol and ether.

Applications

Veratraldehyde was used in the preparation of 4-chloromethyl-2-(dimethoxyphenyl)-1,3-dioxolane. It was used in the synthesis of (+)-lithospermic acid, having anti-HIV activity. It forms 1:1 inclusion complexes with cyclodextrins. It reacts with 3-acetyl-2,5-dimethythiophene to yield chalcone dye, (2E)-3-(3,4-Dimethoxyphenyl)-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one.

Notes

Air sensitive. Incompatible with oxidizing agents.

Literature References

Tirumala G.Varadaraju; Jih Ru Hwu. Synthesis of anti-HIV lithospermic acid by two diverse strategies. Organic & Biomolecular Chemistry. 2012, 10,(28), 5456-5465.

 

Abdullah M.Asiri; Hadi M.Marwani; Salman A.Khan; Samy A.El-Daly. Investigation of spectroscopic behaviors of newly synthesized (2E)-3-(3,4-dimethoxyphenyl)-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one (DDTP) dye. Journal of Fluorescence. 2013, 23,(6), 1271-1278.

Can be used to protect diols as their cyclic 3,4-dimethoxybenzylidene acetals: Tetrahedron, 43, 2549 (1987).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,9951
Beilstein
473899
Harmonized Tariff Code
2912.49
TSCA
Yes
RTECS
YX5088000

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