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5500-21-0 - Cyclopropanecarbonitrile, 98% - Cyanocyclopropane - Cyclopropyl cyanide - A11125 - Alfa Aesar

A11125 Cyclopropanecarbonitrile, 98%

CAS Number
5500-21-0
Synonyms
Cyanocyclopropane
Cyclopropyl cyanide

Size Price ($) Quantity Availability
10g 34.30
50g 82.71
250g 363.59
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Cyclopropanecarbonitrile, 98%

MDL
MFCD00001269
EINECS
226-836-8

Chemical Properties

Formula
C4H5N
Formula Weight
67.09
Boiling Point
134-135°
Flash Point
32°(89°F)
Density
0.905
Refractive Index
1.4210
Solubility
Miscible with water.

Applications

Cyclopropanecarbonitrile is used to prepare cis and trans crotonitrile and allyl cyanide. Further, it reacts with phenylmagnesium bromide to give cyclopropyl-phenyl ketone-imine.

Notes

Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.

Literature References

Yang, X.; Nath, D.; Fleming, F. F. Chemoselective Alkylations with N- and C-Metalated Nitriles. Org. Lett. 2015, 17 (19), 4906-4909.

Huang, H.; Ji, X.; Xiao, F.; Deng, G. J. Copper(I)/Lewis acid triggered ring-opening coupling reaction of cyclopropenes with nitriles. RSC Adv. 2015, 5 (33), 26335-26338.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H330-H226

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Flammable liquid and vapour.

Precautionary Statements: P210-P260-P301+P310-P303+P361+P353-P304+P340-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
635790
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2926.90
TSCA
Yes

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