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A11125 Cyclopropanecarbonitrile, 98%

CAS Number
5500-21-0
Synonyms
Cyanocyclopropane
Cyclopropyl cyanide

Stock No. Size Price ($) Quantity Availability
A11125-09 10g 36.40
A11125-18 50g 85.20
A11125-30 250g 375.00
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Cyclopropanecarbonitrile, 98%

MDL
MFCD00001269
EINECS
226-836-8

Chemical Properties

Formula
C4H5N
Formula Weight
67.09
Boiling Point
134-135°
Flash Point
32°(89°F)
Density
0.905
Refractive Index
1.4210
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water.

Applications

Cyclopropanecarbonitrile is used to prepare cis and trans crotonitrile and allyl cyanide. Further, it reacts with phenylmagnesium bromide to give cyclopropyl-phenyl ketone-imine.

Notes

Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.

Literature References

Yang, X.; Nath, D.; Fleming, F. F. Chemoselective Alkylations with N- and C-Metalated Nitriles. Org. Lett. 2015, 17 (19), 4906-4909.

Huang, H.; Ji, X.; Xiao, F.; Deng, G. J. Copper(I)/Lewis acid triggered ring-opening coupling reaction of cyclopropenes with nitriles. RSC Adv. 2015, 5 (33), 26335-26338.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H301-H311-H315-H319-H331-H335

Flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. Toxic if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P311-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
635790
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2926.90
TSCA
Yes

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