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75-64-9 - tert-Butylamine, 98% - 2-Amino-2-methylpropane - A11135 - Alfa Aesar

A11135 tert-Butylamine, 98%

CAS Number
75-64-9
Synonyms
2-Amino-2-methylpropane

Size Price ($) Quantity Availability
500ml 26.27
2500ml 74.26
10000ml 183.20
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tert-Butylamine, 98%

MDL
MFCD00008050
EINECS
200-888-1

Chemical Properties

Formula
(CH3)3CNH2
Formula Weight
73.14
Melting point
-67°
Boiling Point
44-46°
Flash Point
-38°(-36°F)
Density
0.696
Refractive Index
1.3780
Sensitivity
Air Sensitive
Solubility
Miscible with water, alcohol, ether, chloroform and organic solvents.

Applications

tert-butylamine is used as a precursor for the preparation of rubber accelerators, pharmaceuticals and dyes. It is employed in synthesis of N-tert-butyl-acetamide, isoquinolines, pyridines, decumbenine, sulfontes, sulfonamides and methyl beta-ketophosphonate. It is also used in the study the effect of amines in influencing atmospheric sulfuric acid - water nucleation, hydroamination of terminal alkynes and measuring the surface acidity of solid catalyst. It acts as an indicator molecule in the study of NMR -based pH determination method.

Notes

Air sensitive. Incompatible with strong oxidizing agents, strong acids and acid anhydrides.

Literature References

Szabo, Z. I.; Reti, Z. Z.; Gagyi, L.; Kis, E. L.; Sipos, E. Simultaneous Quantification of Related Substances of Perindopril Tert-Butylamine Using a Novel Stability Indicating Liquid Chromatographic Method. J. Chromatogr. Sci. 2015, 53 (3), 424-430.

Dobrzycki, L.; Taraszewska, p.; Boese, R.; Cyranski, M. K.; Cirkel, S. A. Towards Clathrates: Frozen States of Hydration of tert-Butylamine. Angew. Chem. Int. Ed. 2015, 54 (35), 10138-10144.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H331-H314-H318-H402-H412

Highly flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Precautionary Statements: P210-P260-P261-P273-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,1545
Beilstein
605267
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2921.19
TSCA
Yes
RTECS
EO3330000

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