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A11135 tert-Butylamine, 98%

CAS Number
75-64-9
Synonyms
2-Amino-2-methylpropane

Stock No. Size Price ($) Quantity Availability
A11135-AP 500ml 27.20
A11135-0F 2500ml 78.40
A11135-0D 10000ml 251.00
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tert-Butylamine, 98%

MDL
MFCD00008050
EINECS
200-888-1

Chemical Properties

Formula
(CH3)3CNH2
Formula Weight
73.14
Melting point
-67°
Boiling Point
44-46°
Flash Point
-38°(-36°F)
Density
0.696
Refractive Index
1.3780
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Miscible with water, alcohol, ether, chloroform and organic solvents.

Applications

tert-butylamine is used as a precursor for the preparation of rubber accelerators, pharmaceuticals and dyes. It is employed in synthesis of N-tert-butyl-acetamide, isoquinolines, pyridines, decumbenine, sulfontes, sulfonamides and methyl beta-ketophosphonate. It is also used in the study the effect of amines in influencing atmospheric sulfuric acid - water nucleation, hydroamination of terminal alkynes and measuring the surface acidity of solid catalyst. It acts as an indicator molecule in the study of NMR -based pH determination method.

Notes

Air sensitive. Incompatible with strong oxidizing agents, strong acids and acid anhydrides.

Literature References

Szabo, Z. I.; Reti, Z. Z.; Gagyi, L.; Kis, E. L.; Sipos, E. Simultaneous Quantification of Related Substances of Perindopril Tert-Butylamine Using a Novel Stability Indicating Liquid Chromatographic Method. J. Chromatogr. Sci. 2015, 53 (3), 424-430.

Dobrzycki, L.; Taraszewska, p.; Boese, R.; Cyranski, M. K.; Cirkel, S. A. Towards Clathrates: Frozen States of Hydration of tert-Butylamine. Angew. Chem. Int. Ed. 2015, 54 (35), 10138-10144.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H331-H335-H373

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1545
Beilstein
605267
Hazard Class
8
Packing Group
I
Harmonized Tariff Code
2921.19
TSCA
Yes
RTECS
EO3330000

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