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2,5-Dichloroaniline was used in a study to develop a fast and sensitive quantitative method for the detection of some aniline derivatives by solid-phase microextraction in gas chromatography-mass spectrometry.
Sakurai, T.; Sundaralingam, M.; G. A. Jeffrey, G.A. A nuclear quadrupole resonance and X-ray study of the crystal structure of 2,5-dichloroaniline. Acta Cryst. 1963, 16, 354-363.
Evgen ev, M.I.; Evgen eva, I.I.; Garmonov,S. Yu.; Ismailova, R. N. Sorption-Chromatographic Determination of Aniline, 4-Chloroaniline, and 2,5-Dichloroaniline in Air. Journal of Analytical Chemistry. 2003, 58, (6), 542-547.
Nucleophilic displacement of the chloro-substituents has been carried out by heating with thiophenol in the presence of K2CO3 in NMP: J. Org. Chem., 56, 862 (1991).
Hazard Statements: H301-H311-H331-H373-H500
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure. May form combustible dust concentrations in air
Precautionary Statements: P260-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P311-P312-P314-P330-P361-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. Rinse mouth. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant