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1193-55-1 - 2-Methylcyclohexane-1,3-dione, 98+% - A11218 - Alfa Aesar

A11218 2-Methylcyclohexane-1,3-dione, 98+%

CAS Number
1193-55-1
Synonyms

Size Price ($) Quantity Availability
5g 28.08
25g 87.84
100g 248.45
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2-Methylcyclohexane-1,3-dione, 98+%

MDL
MFCD00001587
EINECS
214-773-9

Chemical Properties

Formula
C7H10O2
Formula Weight
126.16
Melting point
204-208°
Sensitivity
Hygroscopic
Solubility
Soluble in methanol ( 0.1 g/mL). Insoluble in water.

Applications

2-Methylcyclohexane-1,3-dione acts as a synthetic intermediate. It is an important starting material, exemplified in a formal synthesis of acorone. It is also used in Organic Synthesis, Pharmaceuticals, Agrochemicals.

Notes

Hygroscopic. Store at -20°C. Incompatible with oxidizing agents and moisture.

Literature References

Tetsuji Yanami; Michiharu Kato; Masaaki Miyashita; Akira Yoshikoshi, Yasuhiro Itagaki; Kenji Matsuura. Oxygen transfer reaction in acetonylation of 2-methylcyclohexane-1,3-dione with 2-nitropropene. J. Org. Chem. 1977, 42, (16), 2779-2781.

Useful building block for ring B of the steroid nucleus: J. Am. Chem. Soc., 79, 5542 (1957); J. Chem. Soc., 3441 (1957); Helv. Chim. Acta, 36, 482 (1953). For C-methylation using MeI and Benzyl­trimethyl­ammonium hydroxide, A14927, see: Org. Synth. Coll., 8, 312 (1993).

Other References

Beilstein
1281598
Harmonized Tariff Code
2914.29
TSCA
No

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