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Terephthaloyl chloride acts as a monomer with p-phenylenediamine used in the preparation of polymer viz. poly paraphenylene terephthalamide. It is an active component in performance polymers and aramid fibers, which gives flame resistance, chemical resistance, temperature stability, light weight, and very high strength. It is also used as an effective water scavenger, utilized to stabilize isocyanates and urethane prepolymers. Further, it is used in the preparation of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates. In addition to this, it is involved in the condensation reaction with difunctional alfa, µ-diaminopolystyrene to get chain-extended polystyrene containing amide bonds along the polymer backbone.
Ali, W.; Kausar, A.; Iqbal, T. Reinforcement of high performance polystyrene/polyamide/polythiophene with multi-walled carbon nanotube obtained through various routes. Compos. Interfaces 2015, 22 (9), 885-897.
Wan, J.; Gan, B.; Li, C.; Molina-Aldareguia, J.; Li, Z.; Wang, X.; Wang, D. Y. A novel biobased epoxy resin with high mechanical stiffness and low flammability: synthesis, characterization and properties. J. Mater. Chem. A 2015, 3 (43), 21907-21921.
Hazard Statements: H314-H331-H335
Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation.
Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant