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A11285 2-Bromobenzyl bromide, 98%

CAS Number
3433-80-5
Synonyms
alpha,2-Dibromotoluene

Stock No. Size Price ($) Quantity Availability
A11285-09 10g 43.00
A11285-18 50g 122.00
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2-Bromobenzyl bromide, 98%

MDL
MFCD00000173
EINECS
222-334-8

Chemical Properties

Formula
C7H6Br2
Formula Weight
249.94
Melting point
29-32°
Boiling Point
127-129°/19mm
Flash Point
>110°(230°F)
Refractive Index
1.6190
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

2-Bromobenzyl bromide was used in the synthesis of substituted quinazolines and 1,2,3,4-tetrahydroquinazolines, 2- and 3-substituted indenes, tris-2-bromotribenzylamine3.

Notes

Store away from strong bases and oxidizing agents. Incompatible with amines, alcohols, steel.

Literature References

Ronald L. Halterman; Chengian Zhu. Efficient synthesis of 2- and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr(II)/Ni(II)-mediated carbonyl addition sequence. Tetrahedron letters 1999, 40, 7445-7448.

Yao Dai; Xiujuan Feng; Hesong Liu; Hua Jiang and Ming Bao. Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. J. Org. Chem.2011, 76, (24)10068-10077.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H331

Causes severe skin burns and eye damage. Toxic if inhaled.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
971015
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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