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110-83-8 - Cyclohexene, 99% - A11359 - Alfa Aesar

A11359 Cyclohexene, 99%

CAS Number
110-83-8
Synonyms

Size Price ($) Quantity Availability
100ml 19.10
500ml 27.90
2500ml 117.00
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Cyclohexene, 99%

MDL
MFCD00001539
EINECS
203-807-8

Chemical Properties

Formula
C6H10
Formula Weight
82.15
Melting point
-104°
Boiling Point
83-85°
Flash Point
-20°(-4°F)
Density
0.811
Refractive Index
1.4460
Solubility
Immiscible with cold water.

Applications

Cyclohexene is used as a solvent. It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide.

Notes

Incompatible with strong oxidizing agents.

Literature References

Protection of the phenolic OH of tyrosine as the cyclohexyl ether has been effected with BF3 etherate. The group can be cleaved with HF or HBr/AcOH: J. Am. Chem. Soc., 100, 3559 (1978).

Hydrogen donor in catalytic hydrogen-transfer reactions, usually with palladium. For reviews, see: Chem. Rev., 74, 567 (1974); 85, 129 (1985). Examples:

Hydrogenolysis of benzyloxycarbonyl groups: Synthesis, 685 (1976). Simultaneous cleavage of benzyl and benzyloxycarbonyl groups: J. Chem. Soc., Perkin 1, 490 (1977). Cleavage of benzyl ethers: Synthesis, 396 (1981). With FeCl3, reduction of aryl carbonyl groups to methylene: J. Chem. Soc., Chem. Commun., 757 (1976).

Conditions have been described for work-up of the ozonide to give the monoacetal of the dialdehyde, the aldehydo-ester, or the dimethyl acetal of the methyl ester: Org. Synth. Coll., 7, 168 (1990).

Undergoes allylic acetoxylation, catalyzed by Palladium(II)­ acetate, 10516 , in the presence of MnO2 and 1,4-benzoquinone: Org. Synth. Coll., 8, 137 (1993).

Xu, L. Q.; Chen, J. C.; Qian, S. S.; Zhang, A. K.; Fu, G. D.; Li, C. M.; Kang, E. T. PEGylated Metalloporphyrin Nanoparticles as a Promising Catalyst for the Heterogeneous Oxidation of Cyclohexene in Water. Macromol. Chem. Phys. 2015, 216 (4), 417-426.

Hu, X.; Shi, Y.; Zhang, Y.; Zhu, B.; Zhang, S.; Huang, W. Nanotubular TiO2-supported amorphous Co-B catalysts and their catalytic performances for hydroformylation of cyclohexene. Catal. Commun. 2015, 59, 45-49.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H304

Highly flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways.

Precautionary Statements: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,2727
Beilstein
906737
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2902.19
TSCA
Yes
RTECS
GW2500000

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